Investigating the Effect of Thermal Annealing and Changing the Concentration of GO in GO/PVA Nanocomposites on Their Structural, Electrical, and Optical Properties

被引:14
作者
Gahramanli, Lala [1 ,2 ]
Muradov, Mustafa [1 ]
Eyvazova, Goncha [1 ]
Baghirov, Mahammad Baghir [1 ]
Mammadyarova, Sevinj [1 ]
Aliyeva, Gunel [1 ]
Hajiyev, Elman [3 ]
Mammadov, Faig [4 ]
Bellucci, Stefano [2 ]
机构
[1] Baku State Univ, Nano Res Lab, 23 Acad Zahid Khalilov St, Baku AZ1148, Azerbaijan
[2] INFN Lab Nazl Frascati, Via E Fermi 54, I-00044 Frascati, Italy
[3] Azerbaijan Natl Acad Sci, Inst Phys, H Javid Av 131, Baku AZ1143, Azerbaijan
[4] Azerbaijan Natl Acad Sci, Inst Catalysis & Inorgan Chem, H Javid Av131, Baku AZ1143, Azerbaijan
关键词
GO/PVA nanocomposites; the influence of thermal annealing; concentration; physical properties; band gap value; GRAPHENE OXIDE; POLYVINYL-ALCOHOL; BAND-GAP; POLY(VINYL; DEGRADATION; DECOMPOSITION; NANOPARTICLES; COMPOSITES;
D O I
10.3390/chemengineering7050092
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The present research involves producing graphene oxide (GO) using the Hummers method, generating a composite using GO and PVA, and analyzing these composites' structural and optical characteristics. PVA and GO were used in varied percentages to deal with the issue of how the features of GO/PVA alter depending on concentration. The impact of thermal annealing on the structure and optical characteristics of GO/PVA materials at various concentrations were also investigated. UV-VIS was used to investigate the band gap value of GO/PVA composites. The band gap value changed due to an increase in the concentration of GO in the composites in the PVA and the impact of thermal annealing. The band gap value, specific resistance, and dielectric constant were all found to be well controlled by varying the thermal annealing temperature and the concentration of GO in this case. Differential Scanning Calorimetry (DSC) and thermogravimetric analysis (TGA) were performed on pure PVA and GO/PVA samples in various percentages of GO in order to examine the effect of temperature on the physical properties of (n = 1, 2, 3, 5, 20%) nGO%/PVA nanocomposites. Thermal stability increased as the fraction of GO in the PVA polymer matrix increased.
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页数:20
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