4-Terminal Inorganic Perovskite/Organic Tandem Solar Cells Offer 22% Efficiency

被引：56

作者：

Liu, Ling ^{[1
]}

Xiao, Hanrui ^{[1
,2
]}

Jin, Ke ^{[1
]}

Xiao, Zuo ^{[1
]}

Du, Xiaoyan ^{[3
]}

Yan, Keyou ^{[4
]}

Hao, Feng ^{[5
]}

Bao, Qinye ^{[6
]}

Yi, Chenyi ^{[7
]}

Liu, Fangyang ^{[2
]}

Wang, Wentao ^{[8
]}

Zuo, Chuantian ^{[1
,9
]}

Ding, Liming ^{[1
]}

机构：

[1] Ctr Excellence Nanosci CAS, Natl Ctr Nanosci & Technol, Key Lab Nanosyst & Hierarch Fabricat CAS, Beijing 100190, Peoples R China

[2] Cent South Univ, Sch Met & Environm, Changsha 410083, Peoples R China

[3] Shandong Univ, Sch Phys, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

[4] South China Univ Technol, Sch Environm & Energy, Guangzhou 510000, Peoples R China

[5] Univ Elect Sci & Technol China, Sch Mat & Energy, Chengdu 610054, Peoples R China

[6] East China Normal Univ, Sch Phys & Elect Sci, Shanghai 200241, Peoples R China

[7] Tsinghua Univ, Dept Elect Engn, State Key Lab Power Syst, Beijing 100084, Peoples R China

[8] Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Hangzhou 310018, Peoples R China

[9] Chinese Acad Sci, Inst Semicond, Key Lab Semicond Mat Sci, Beijing Key Lab Low Dimens Semicond Mat & Devices, Beijing 100083, Peoples R China

来源：

NANO-MICRO LETTERS | 2023年 / 15卷 / 01期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

4-Terminal tandem solar cells; Inorganic perovskite solar cells; Organic solar cells; Semitransparent; Drop-coating;

D O I：

10.1007/s40820-022-00995-2

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

After fast developing of single-junction perovskite solar cells and organic solar cells in the past 10 years, it is becoming harder and harder to improve their power conversion efficiencies. Tandem solar cells are receiving more and more attention because they have much higher theoretical efficiency than single-junction solar cells. Good device performance has been achieved for perovskite/silicon and perovskite/perovskite tandem solar cells, including 2-terminal and 4-terminal structures. However, very few studies have been done about 4-terminal inorganic perovskite/organic tandem solar cells. In this work, semi-transparent inorganic perovskite solar cells and organic solar cells are used to fabricate 4-terminal inorganic perovskite/organic tandem solar cells, achieving a power conversion efficiency of 21.25% for the tandem cells with spin-coated perovskite layer. By using drop-coating instead of spin-coating to make the inorganic perovskite films, 4-terminal tandem cells with an efficiency of 22.34% are made. The efficiency is higher than the reported 2-terminal and 4-terminal inorganic perovskite/organic tandem solar cells. In addition, equivalent 2-terminal tandem solar cells were fabricated by connecting the sub-cells in series. The stability of organic solar cells under continuous illumination is improved by using semi-transparent perovskite solar cells as filter.

引用

页数：10

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