Separation of Ethyl Acetate and Ethanol Azeotropic System by Acetate-Based Ionic Liquid

被引：0

作者：

Li, Wenxiu ^{[1
]}

Zhang, Linzi ^{[1
]}

He, Xin ^{[1
]}

Ni, Qingfeng ^{[1
]}

Zhang, Tao ^{[1
]}

机构：

[1] Shenyang Univ Chem Technol, Liaoning Prov Key Lab Chem Separat Technol, Shenyang 110142, Peoples R China

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2024年 / 53卷 / 08期

基金：

美国国家科学基金会;

关键词：

Vapor-liquid equilibrium; Ethyl acetate; NRTL model; Ethanol; Ionic liquids; EXTRACTIVE DISTILLATION; PLUS METHANOL; VAPOR; EQUILIBRIUM; MIXTURE; CARBONATE;

D O I：

10.1007/s10953-023-01361-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three ionic liquids (ILs)(1-ethyl-2,3-dimethylimidazolium acetate, [EMMIM][AC]; tributyl-methylammonium acetate, [N-4,N-4,N-4,N-1][AC]; and tetraethylammonium acetate, [N-2,N-2,N-2,N-2][AC]) were chosen. The vapor-liquid equilibrium (VLE) data of ternary mixtures (acetate + ethanol + IL) were measured at 101.3 KPa. NRTL equation was used to correlate the data. From NRTL model, for [N-2,N-2,N-2,N-2][AC], [EMMIM][AC], and [N-4,N-4,N-4,N-1][AC], minimum mole fractions for completely eliminating azeotrope are 0.015, 0.020 and 0.022, respectively. From the average relative volatility and sigma-profiles, it can be obtained that the separation ability order is [EMMIM][AC] > [N-2,N-2,N-2,N-2][AC] > [N-4,N-4,N-4,N-1][AC].

引用

页码：1052 / 1073

页数：22

共 62 条

[51] Study on the Isobaric Vapor-Liquid Equilibrium Behavior of the Methanol plus Methyl Ethyl Ketone System Using Ionic Liquids as Extractants and Model Correlation [J].

Wu, Tianzhao ;

Yin, Chaoyue ;

Zhang, Aidi ;

Xin, Hua ;

Lv, Meiheng ;

Lin, Tong ;

Lu, Yao ;

Wang, Yangyang ;

Song, Tinghe ;

Li, Shunmin ;

Zhang, Qinqin ;

Zhang, Zhigang .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2022, 67 (09) :2367-2377

[52] Study on the selective separation of methanol and methyl ethyl ketone from the azeotropic system using ionic liquids and their separation mechanism [J].

Wu, Tianzhao ;

Zhang, Qinqin ;

Xin, Hua ;

Li, Shunmin ;

Song, Tinghe ;

Zhang, Zhigang .

JOURNAL OF MOLECULAR LIQUIDS, 2021, 343

[53]

YAWS CL, 1989, HYDROCARB PROCESS, V68, P65

[54] Isobaric vapor-liquid equilibrium for ethyl acetate plus ethanol with ionic liquids [MMIM][DMP] and [OMIM][PF6] as entrainers [J].

Yue, Kun ;

Zhou, Guowei .

JOURNAL OF MOLECULAR LIQUIDS, 2022, 348

[55] Separation of ethyl acetate-ethanol azeotropic mixture using hydrophilic ionic liquids [J].

Zhang, Dong L. ;

Deng, Yue F. ;

Li, Chuan B. ;

Chen, Ji .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (06) :1995-2001

[56] Isobaric vapor-liquid equilibria for water plus ethanol plus ethyl acetate+1-butyl-3-methylimidazolium acetate at low water mole fractions [J].

Zhang, Lianzhong ;

Yuan, Xingcai ;

Qiao, Bingbang ;

Qi, Ruize ;

Ji, Jianbing .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (07) :1595-1601

[57] Separation of the Dimethyl Carbonate plus Ethanol Mixture Using Imidazolium-Based Ionic Liquids as Entrainers [J].

Zhang, Zhigang ;

Lu, Ruizhe ;

Wang, Chenghao ;

Zhang, Qinqin ;

Chen, Jinling ;

Li, Wenxiu .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2020, 65 (04) :1705-1714

[58] COSMO-RS based ionic liquid screening for the separation of acetonitrile and ethanol azeotropic mixture [J].

Zhang, Zhigang ;

Lu, Ruizhe ;

Zhang, Qinqin ;

Chen, Jinling ;

Li, Wenxiu .

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2020, 95 (04) :1191-1202

[59] Separation of ethyl acetate and ethanol azeotrope mixture using dialkylphosphates-based ionic liquids as entrainers [J].

Zhang, Zhigang ;

Wu, Kaifang ;

Zhang, Qinqin ;

Zhang, Tao ;

Zhang, Debiao ;

Yang, Ru ;

Li, Wenxiu .

FLUID PHASE EQUILIBRIA, 2017, 454 :91-98

[60] Separation of ethyl acetate and 2-propanol azeotropic mixture using ionic liquids as entrainers [J].

Zhang, Zhigang ;

Zhang, Aidi ;

Wu, Kaifang ;

Zhang, Qinqin ;

Hu, Angran ;

Li, Wenxiu .

FLUID PHASE EQUILIBRIA, 2016, 429 :331-338

← 1 2 3 4 5 6 7 →