Tailored nonwoven supported non-flammable quasi-solid electrolyte enables an ultra-stable sodium metal battery

被引:2
作者
Das, Sayan [1 ,2 ]
Pol, Vilas G. [2 ]
Adyam, Venimadhav [1 ]
机构
[1] IIT Kharagpur, Cryogen Engn Ctr, Kharagpur 721302, W Bengal, India
[2] Purdue Univ, Davidson Sch Chem Engn, W Lafayette, IN 47907 USA
来源
ENERGY ADVANCES | 2024年 / 3卷 / 02期
关键词
LITHIUM; ISSUES;
D O I
10.1039/d3ya00435j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An easily scalable approach to developing a nonwoven-supported PVDF-HFP polymer-based quasi-solid-state flexible non-flammable electrolyte shows a conductivity of 1.16 x 10-4 S cm-1 at RT with a transfer number of 0.68. The Na3V2 (PO4)3 (NVP) cathode-based Na metal cell delivers a discharge capacity of 73 mAh g-1 at a 2C rate and shows exceptional capacity retention of 98.4% after 2500 cycles. We present an easily scalable approach to developing a nonwoven-supported PVDF-HFP polymer-based quasi-solid-state flexible non-flammable electrolyte, with a conductivity of 1.16 x 10-4 S cm-1 at RT with a transfer number of 0.68.
引用
收藏
页码:419 / 423
页数:5
相关论文
共 34 条
[11]   Stabilizing Interfacial Reactions for Stable Cycling of High-Voltage Sodium Batteries [J].
Jin, Yan ;
Xu, Yaobin ;
Xiao, Biwei ;
Engelhard, Mark H. ;
Yi, Ran ;
Vo, Thanh D. ;
Matthews, Bethany E. ;
Li, Xiaolin ;
Wang, Chongmin ;
Le, Phung M. L. ;
Zhang, Ji-Guang .
ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (40)
[12]   Pure β-phase formation in polyvinylidene fluoride (PVDF)-carbon nanotube composites [J].
Kabir, Ekramul ;
Khatun, M. ;
Nasrin, L. ;
Raihan, Mustafa J. ;
Rahman, M. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2017, 50 (16)
[13]   Electrochemical and cycling performances of novel nonafluorobutanesulfonate (nonaflate) ionic liquid based ternary gel polymer electrolyte membranes for rechargeable lithium ion batteries [J].
Karuppasamy, K. ;
Reddy, P. Anil ;
Sriniyas, G. ;
Tewari, Amit ;
Sharma, Ramakant ;
Shajan, X. Sahaya ;
Gupta, Dipti .
JOURNAL OF MEMBRANE SCIENCE, 2016, 514 :350-357
[14]   A hybridized solid-gel nonflammable Li-Battery [J].
Li, Guibin ;
Chen, Xin ;
Miao, Lixiao ;
Chen, Jitao ;
Zheng, Junrong .
JOURNAL OF POWER SOURCES, 2018, 394 :26-34
[15]   A review on the key issues for lithium-ion battery management in electric vehicles [J].
Lu, Languang ;
Han, Xuebing ;
Li, Jianqiu ;
Hua, Jianfeng ;
Ouyang, Minggao .
JOURNAL OF POWER SOURCES, 2013, 226 :272-288
[16]   Recent Progress on Integrated Energy Conversion and Storage Systems [J].
Luo, Bin ;
Ye, Delai ;
Wang, Lianzhou .
ADVANCED SCIENCE, 2017, 4 (09)
[17]   From Lithium-Ion to Sodium-Ion Batteries: Advantages, Challenges, and Surprises [J].
Nayak, Prasant Kumar ;
Yang, Liangtao ;
Brehm, Wolfgang ;
Adelhelm, Philipp .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (01) :102-120
[18]   Solid electrolytes for solid-state Li/Na-metal batteries: inorganic, composite and polymeric materials [J].
Song, Shufeng ;
Hu, Ning ;
Lu, Li .
CHEMICAL COMMUNICATIONS, 2022, 58 (86) :12035-12045
[19]   Microporous ceramic coated separators with superior wettability for enhancing the electrochemical performance of sodium-ion batteries [J].
Suharto, Yustian ;
Lee, Yongho ;
Yu, Ji-Sang ;
Choi, Wonchang ;
Kim, Ki Jae .
JOURNAL OF POWER SOURCES, 2018, 376 :184-190
[20]   A safe and non-flammable sodium metal battery based on an ionic liquid electrolyte [J].
Sun, Hao ;
Zhu, Guanzhou ;
Xu, Xintong ;
Liao, Meng ;
Li, Yuan-Yao ;
Angell, Michael ;
Gu, Meng ;
Zhu, Yuanmin ;
Hung, Wei Hsuan ;
Li, Jiachen ;
Kuang, Yun ;
Meng, Yongtao ;
Lin, Meng-Chang ;
Peng, Huisheng ;
Dai, Hongjie .
NATURE COMMUNICATIONS, 2019, 10 (1)