Ferroelectric hybrid organic-inorganic perovskites and their structural and functional diversity

This review discusses the structural design and superior performance of organic-inorganic hybrid perovskite ferroelectrics and proposes their opportunities, challenges and future molecular ferroelectric development directions. Molecular ferroelectrics have gradually aroused great interest in both fundamental scientific research and technological applications because of their easy processing, light weight and mechanical flexibility. Hybrid organic-inorganic perovskite ferroelectrics (HOIPFs), as a class of molecule-based ferroelectrics, have diverse functionalities owing to their unique structure and have become a hot spot in molecular ferroelectrics research. Therefore, they are extremely attractive in the field of ferroelectrics. However, there seems to be a lack of systematic review of their design, performance and potential applications. Herein, we review the recent development of HOIPFs from lead-based, lead-free and metal-free perovskites, and outline the versatility of these ferroelectrics, including piezoelectricity for mechanical energy-harvesting and optoelectronic properties for photovoltaics and light detection. Furthermore, a perspective view of the challenges and future directions of HOIPFs is also highlighted.