Novel MCM-41 Supported Dicationic Imidazolium Ionic Liquids Catalyzed Greener and Efficient Regioselective Synthesis of 2-Oxazolidinones from Aziridines and Carbon Dioxide

被引：7

作者：

Hu, Yulin ^{[1
]}

Yang, Lili ^{[1
]}

Liu, Xiaobing ^{[2
]}

机构：

[1] Anshun Univ, Coll Chem & Chem Engn, Anshun 561000, Peoples R China

[2] Jinggangshan Univ, Coll Chem & Chem Engn, Jian 343009, Peoples R China

来源：

MOLECULES | 2023年 / 28卷 / 01期

基金：

中国国家自然科学基金;

关键词：

supported ionic liquid; CO2; conversion; aziridines; 2-oxazolidinones; sustainability; RECYCLABLE CATALYST; SELECTIVE SYNTHESIS; CO2; 5-ARYL-2-OXAZOLIDINONES; CYCLOADDITION; EPOXIDES; FIXATION;

D O I：

10.3390/molecules28010242

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A type of MCM-41 supported dicationic imidazolium ionic liquid nanocatalyst has been synthesized and found to be competent for the synthesis of 2-oxazolidinones through the sustainable chemical conversion of CO2 with aziridines. It was shown that the highest efficiency was achieved in the cycloaddition of a series of aziridines and CO2 in the presence of a catalytic amount of the solid catalyst MCM-41@ILLaCl4 under mild conditions. Merits of this meticulously designed protocol are the use of a novel supported ionic liquid catalyst, the easy work-up process, good to excellent yields, a short reaction time, and purification without column chromatography. Overall, the present protocol of synthesizing 2-oxazolidinones under cocatalyst- and solvent-free conditions using MCM-41@ILLaCl4 is promising for industrial applications.

引用

页数：11

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