Cooperative effects of Mo and B additions on the microstructure and mechanical properties of multi-elemental Nb-Si-Ti based alloys

被引:10
作者
Li, Zhaobo [1 ]
Luo, Liangshun [1 ]
Wang, Binbin [1 ]
Su, Baoxian [1 ]
Luo, Lei [2 ]
Wang, Liang [1 ]
Su, Yanqing [1 ]
Guo, Jingjie [1 ]
Fu, Hengzhi [1 ]
机构
[1] Harbin Inst Technol, Sch Mat Sci & Engn, Natl Key Lab Precis Hot Proc Met, Harbin 150001, Peoples R China
[2] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Nanjing 210016, Peoples R China
基金
中国国家自然科学基金;
关键词
Microstructure; Fracture toughness; High-temperature compression strength; Orientation relationship; HIGH-TEMPERATURE STRENGTH; SOLID PHASE-EQUILIBRIA; FRACTURE-TOUGHNESS; OXIDATION RESISTANCE; ORIENTATION RELATIONSHIP; EVOLUTION; COMPOSITES; CR; BEHAVIOR; RECRYSTALLIZATION;
D O I
10.1016/j.matchar.2023.113421
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The multi-elemental Nb-Si-Ti based alloys with Mo and B additions are prepared by vacuum non-consumable arc melting. The cooperative effects of Mo and B additions on the microstructure, room-temperature fracture and high-temperature compressive strength are investigated. The additions of Mo and B basically cannot affect the constituent phases of the Nb-Si-Ti based alloys. The fracture toughness of Nb-Si-Ti based alloys is deteriorated by alloying with Mo or B individually. However, the cooperative additions of Mo and B inversely increases the fracture toughness, owing to the existence of chaotic eutectics. Moreover, the individual or cooperative additions of Mo and B distinctly increase the high-temperature compressive strength at 1200 degrees C due to the solution strengthening effects of Mo and B. Among all alloys, the 1Mo-2B alloy not only exhibits the highest roomtemperature fracture toughness (15.99 MPa center dot m1/2) because of the numerous chaotic eutectics and low proportion of primary alpha-Nb5Si3, but also maintains the high-temperature compressive strength of 286 MPa. Furthermore, many orientation relationships between Nbss and Nb5Si3 are observed in 1Mo-2B and 3Mo-4B alloys.
引用
收藏
页数:18
相关论文
共 70 条
[1]   FLOW CHARACTERISTICS OF HIGHLY CONSTRAINED METAL WIRES [J].
ASHBY, MF ;
BLUNT, FJ ;
BANNISTER, M .
ACTA METALLURGICA, 1989, 37 (07) :1847-1857
[2]   Chlorination treatment to improve the oxidation resistance of Nb-Mo-Si-B alloys [J].
Behrani, V ;
Thom, AJ ;
Kramer, MJ ;
Akinc, M .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2005, 36A (03) :609-615
[3]   The Nb-Ti-Si ternary phase diagram: Evaluation of liquid-solid phase equilibria in Nb- and Ti-rich alloys [J].
Bewlay, BP ;
Jackson, MR ;
Lipsitt, HA .
JOURNAL OF PHASE EQUILIBRIA, 1997, 18 (03) :264-278
[4]   The balance of mechanical and environmental properties of a multielement niobium-niobium silicide-based in situ composite [J].
Bewlay, BP ;
Jackson, MR ;
Lipsitt, HA .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1996, 27 (12) :3801-3808
[5]   Alloying effects on the fracture toughness of Nb-based silicides and Laves phases [J].
Chan, KS .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2005, 409 (1-2) :257-269
[6]   The fracture resistance and crack tip micromechanics of in-situ intermetallic composites [J].
Chan, KS ;
Davidson, DL .
JOM-JOURNAL OF THE MINERALS METALS & MATERIALS SOCIETY, 1996, 48 (09) :62-67
[7]   Improving the fracture toughness of constituent phases and Nb-based in-situ composites by a computational alloy design approach [J].
Chan, KS ;
Davidson, DL .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2003, 34A (09) :1833-1849
[8]   The fracture toughness of niobium-based, in situ composites [J].
Chan, KS .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1996, 27 (09) :2518-2531
[9]   Alloying effects on fracture mechanisms in Nb-based intermetallic in-situ composites [J].
Chan, KS .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2002, 329 :513-522
[10]   Relationships of fracture toughness and dislocation mobility in intermetallics [J].
Chan, KS .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2003, 34A (10) :2315-2328