Semi-Transparent Blade-Coated FAPbBr3 Perovskite Solar Cells: A Scalable Low-Temperature Manufacturing Process under Ambient Condition

被引:30
作者
Barichello, Jessica [1 ,2 ]
Di Girolamo, Diego [1 ]
Nonni, Elisa [1 ]
Paci, Barbara [3 ]
Generosi, Amanda [3 ]
Kim, Minjin [4 ]
Levtchenko, Alexandra [5 ]
Cacovich, Stefania [4 ]
Di Carlo, Aldo [1 ,3 ]
Matteocci, Fabio [1 ]
机构
[1] Univ Roma Tor Vergata, Ctr Hybrid & Organ Solar Energy, Dept Elect Engn, CHOSE, I-00133 Rome, Italy
[2] Ist i Proc Chim Fisici, IPCF CNR, I-98158 Messina, Italy
[3] CNR, Ist Struttura Mat, ISM CNR, I-00133 Rome, Italy
[4] Ecole Polytech, Inst Photovolta Ile Defrance IPVF, UMR 9006, CNRS, F-91120 Palaiseau, France
[5] Inst Photovolta Ile Defrance IPVF, F-91120 Palaiseau, France
关键词
building integrated photovoltaics; low-temperature processing; perovskite solar cells; tandem; transparent photovoltaics; POWER CONVERSION EFFICIENCY; TOP ELECTRODE; PHOTOVOLTAICS; TRANSPARENT; CRYSTALS; COLOR;
D O I
10.1002/solr.202200739
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Perovskite photovoltaics (PVs) is an emerging PV technology that attracts interest thanks to an unprecedented combination of properties, including the ease of the bandgap tunability. The feasibility to deploy wide bandgap absorbers (>2.2 eV) leading to high average visible transmittance (AVT) is particularly intriguing for building-integrated PVs, in particular for smart windows, facades, and agrivoltaics. However, research on this topic is still at the initial stage, especially concerning the development of scalable deposition techniques. Uniform coverage and morphology control of bromide perovskite film are the main issues to tackle. Herein, a systematic study on the development of FAPbBr(3)-based semi-transparent perovskite solar cell (ST-PSC) is presented by replacing spin-coating as the main deposition technique used for the device fabrication. To tackle this topic, the blade coating technique is employed to obtain a manufacturing flow performed at low temperature in the air environment. The results for the blade-coated device show a power conversion efficiency of 5.8%, AVT of 52.3%, and bifacial factor of 86.5%. Moreover, scalable and uniform FAPbBr(3) deposition on 300 cm(2) substrates is presented for the first time. The combination of low temperature, scale-up capability, and air processing along with promising PV performances represent a feasible platform for the future exploitation of PSC in building integrated photovoltaic.
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页数:9
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