Crystal structure of bis[octakis(dimethyl sulfoxidκO)ytterbium(III)] pentabromidoplumbate(II) tribromide dimethyl sulfoxide monosolvate: a ytterbium-doped lead halide perovskite precursor

被引：1
|
作者：
Kinoshita, Takumi [1 ]
Fukumoto, Kanna [2 ]
Segawa, Hiroshi [1 ,2 ]
机构：
[1] Univ Tokyo, Grad Sch Arts & Sci, Meguro Ku, 3-8-1 Komaba, Tokyo 1538902, Japan
[2] Univ Tokyo, Res Ctr Adv Sci & Technol RCAST, Meguro Ku, 4-6-1 Komaba, Tokyo 1538904, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
基金：
日本学术振兴会;
关键词：
lead halide perovskite; ytterbium; photoluminescence; crystal structure; THIN-FILMS; REFINEMENT; COMPLEXES; TIN;
D O I：
10.1107/S2056989023002852
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A mixture of PbBr2 and YbBr3.nH(2)O in a dimethyl sulfoxide (DMSO) solution yielded single crystals of a lead halide perovskite precursor with ytterbium, bis[octakis(dimethyl sulfoxide)ytterbium(III)]pentabromidoplumbate(II) tribromide with dimethyl sulfoxide as co-crystallite, [Yb(C2H6OS)(8)][PbBr5](0.5)Br-1.5.0.5C(2)H(6)OS. The complex ions PbBr53- and Yb(DMSO) (3+)(8) are present in the crystal together with three Br- ions and DMSO molecules. X-ray crystallography revealed that the Br- ions in YbBr3 are replaced by the solvent and bound to a Pb-II atom or remain free. The presence of PbBr53- units, which are molecular ions with a square-pyramidal structure, is also observed. These single crystals react with a caesium chloride solution, exhibiting near-infrared (NIR) luminescence by visible photoexcitation, suggesting the formation of Yb3+-doped lead halide perovskites (CsPbBr(3-x)Clx.Yb3+).
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页码：402 / +
页数：10
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