Toward Utilization of Lignin-Derivatized Monomers: Development of Degradable Vanillin-Based Polyurethane Materials

被引:10
作者
Luo, Huali [4 ]
Hua, Xuewen [1 ]
Liu, Wenrui [1 ]
Xu, Yecheng [2 ]
Cao, Fengxiang [2 ]
Nikafshar, Saeid [3 ]
Fang, Zhen [2 ]
机构
[1] Liaocheng Univ, Coll Agr, Liaocheng 252000, Peoples R China
[2] Shandong Lab Yantai Adv Mat & Green Manufacture, Yantai 264006, Peoples R China
[3] Michigan State Univ, Dept Forestry, E Lansing, MI 48824 USA
[4] Yantai Vocat Coll, Food & Biochem Engn Dept, Yantai 264006, Peoples R China
基金
中国国家自然科学基金;
关键词
vanillin; polyurethane; lignin; degradable; biobased material; HIGH-PERFORMANCE; 2,5-FURANDICARBOXYLIC ACID; TEREPHTHALIC ACID; EPOXY VITRIMER; OXIDATION; CHEMICALS; BIOMASS; DEPOLYMERIZATION; LIGNOCELLULOSE;
D O I
10.1021/acsapm.3c00754
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Utilization of biomass-derived monomeric building blocksto formulatepolyurethane materials can significantly reduce the complexity ofthe target network generated by the uncertainty of raw biomass. Herein,in this study, four cleavable vanillin-based polyols were preparedfrom vanillin and two sustainable feedstocks, 2,5-furandicarboxylicacid (FDCA) and terephthalic acid (TPA), followed by the cross-linkingwith two different isocyanates. The resulting polyurethane samplesexhibited reasonable mechanical strength, thermostability, and solventresistance. Of great importance is that the inherent ester bonds inthe network endowed these samples with outstanding degradability,evidenced by the impressive weight loss in aqueous NaOH solution atroom temperature (weight loss of up to & SIM;35% after 24 h). Notably,the glass-transition temperature (T (g))of these materials can be tunable by using different isocyanates,ranging from 26 to 101 & DEG;C in this work, which could potentiallymeet application requirements in different fields. This study providesan encouraging first step in formulating mechanically strong, thermallystable, and easily degradable polyurethane samples that are potentiallyuseful in practical applications (i.e., coating and packaging).
引用
收藏
页码:6061 / 6068
页数:8
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