Unravelling the mechanism of CO2 activation over low-loaded Cu/CeO2(111) catalysts using operando and transient spectroscopies

被引：9
作者：
Ziemba, Marc [1 ]
Hess, Christian [1 ]
机构：
[1] Tech Univ Darmstadt, Eduard Zintl Inst Inorgan & Phys Chem, Alarich Weiss Str 8, D-64287 Darmstadt, Germany
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2023年 / 13卷 / 10期
关键词：
CERIA; REDUCTION; SURFACE; CEO2;
D O I：
10.1039/d3cy00494e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Using operando Raman and UV-vis spectroscopy as well as transient IR spectroscopy, low-loaded Cu/CeO2(111) catalysts were investigated with respect to their redox behavior and the importance of adsorbates for the reverse water-gas shift (rWGS) reaction. Here it is shown that of two possible mechanisms the redox mechanism is predominant over an associative one.
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收藏
页码：2922 / 2926
页数：5
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