MXene: fundamentals to applications in electrochemical energy storage

被引:62
作者
Ampong, Daniel Nframah [1 ]
Agyekum, Emmanuel [2 ]
Agyemang, Frank Ofori [1 ]
Mensah-Darkwa, Kwadwo [1 ]
Andrews, Anthony [1 ]
Kumar, Anuj [3 ]
Gupta, Ram K. [4 ,5 ]
机构
[1] Kwame Nkrumah Univ Sci & Technol, Coll Engn, Dept Mat Engn, Kumasi, Ghana
[2] Hohai Univ, Dept Mat Sci & Engn, Nanjing, Peoples R China
[3] GLA Univ, Dept Chem, Nanotechnol Res Lab, Mathura 281406, Uttar Pradesh, India
[4] Pittsburg State Univ, Natl Inst Mat Advancement, Pittsburg, KS 66762 USA
[5] Pittsburg State Univ, Dept Chem, Pittsburg, KS 66762 USA
关键词
MXene; MAX phases; Intercalation; Surface terminations; Electrochemical energy storage; 2D TITANIUM CARBIDE; PERFORMANCE ELECTRODE MATERIALS; VOLUMETRIC CAPACITANCE; RENEWABLE ENERGY; FILM ELECTRODES; ANODE MATERIAL; MO2CTX MXENE; LITHIUM; TI3C2; EXFOLIATION;
D O I
10.1186/s11671-023-03786-9
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A new, sizable family of 2D transition metal carbonitrides, carbides, and nitrides known as MXenes has attracted a lot of attention in recent years. This is because MXenes exhibit a variety of intriguing physical, chemical, mechanical, and electrochemical characteristics that are closely linked to the wide variety of their surface terminations and elemental compositions. Particularly, MXenes are readily converted into composites with materials including oxides, polymers, and CNTs, which makes it possible to modify their characteristics for a variety of uses. MXenes and MXene-based composites have demonstrated tremendous promise in environmental applications due to their excellent reducibility, conductivity, and biocompatibility, in addition to their well-known rise to prominence as electrode materials in the energy storage sector. The remarkable characteristics of 2D MXene, including high conductivity, high specific surface area, and enhanced hydrophilicity, account for the increasing prominence of its use in storage devices. In this review, we highlight the most recent developments in the use of MXenes and MXene-based composites for electrochemical energy storage while summarizing their synthesis and characteristics. Key attention is paid to applications in supercapacitors, batteries, and their flexible components. Future research challenges and perspectives are also described.
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页数:44
相关论文
共 191 条
[1]   Recent trends in the development of MXenes and MXene-based composites as anode materials for Li-ion batteries [J].
Aghamohammadi, Hamed ;
Eslami-Farsani, Reza ;
Castillo-Martinez, Elizabeth .
JOURNAL OF ENERGY STORAGE, 2022, 47
[2]   Carbon in lithium-ion and post-lithium-ion batteries: Recent features [J].
Ahmad, Y. ;
Colin, M. ;
Gervillie-Mouravieff, C. ;
Dubois, M. ;
Guerin, K. .
SYNTHETIC METALS, 2021, 280
[3]   Lithium-Ion Battery Modeling Including Degradation Based on Single-Particle Approximations [J].
Al-Gabalawy, Mostafa ;
Hosny, Nesreen S. ;
Hussien, Shimaa A. .
BATTERIES-BASEL, 2020, 6 (03) :1-26
[4]   Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers [J].
Anasori, Babak ;
Shi, Chenyang ;
Moon, Eun Ju ;
Xie, Yu ;
Voigt, Cooper A. ;
Kent, Paul R. C. ;
May, Steven J. ;
Billinge, Simon J. L. ;
Barsoum, Michel W. ;
Gogotsi, Yury .
NANOSCALE HORIZONS, 2016, 1 (03) :227-234
[5]   Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes) [J].
Anasori, Babak ;
Xie, Yu ;
Beidaghi, Majid ;
Lu, Jun ;
Hosler, Brian C. ;
Hultman, Lars ;
Kent, Paul R. C. ;
Gogotsi, Yury ;
Barsoum, Michel W. .
ACS NANO, 2015, 9 (10) :9507-9516
[6]   Experimental and theoretical characterization of ordered MAX phases Mo2TiAlC2 and Mo2Ti2AlC3 [J].
Anasori, Babak ;
Dahlqvist, Martin ;
Halim, Joseph ;
Moon, Eun Ju ;
Lu, Jun ;
Hosler, Brian C. ;
Caspi, El'ad N. ;
May, Steven J. ;
Hultman, Lars ;
Eklund, Per ;
Rosen, Johanna ;
Barsoum, Michel W. .
JOURNAL OF APPLIED PHYSICS, 2015, 118 (09)
[7]   Dependence of elastic and optical properties on surface terminated groups in two-dimensional MXene monolayers: a first-principles study [J].
Bai, Yuelei ;
Zhou, Kun ;
Srikanth, Narasimalu ;
Pang, John H. L. ;
He, Xiaodong ;
Wang, Rongguo .
RSC ADVANCES, 2016, 6 (42) :35731-35739
[8]   2D MXenes: Synthesis, properties, and electrochemical energy storage for supercapacitors-A review [J].
Baig, Mutawara Mahmood ;
Gul, Iftikhar Hussain ;
Baig, Sherjeel Mahmood ;
Shahzad, Faisal .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2022, 904
[9]   Nucleation and growth of Ti2AlN thin films deposited by reactive magnetron sputtering onto MgO(111) [J].
Beckers, M. ;
Schell, N. ;
Martins, R. M. S. ;
Muecklich, A. ;
Moeller, W. ;
Hultman, L. .
JOURNAL OF APPLIED PHYSICS, 2007, 102 (07)
[10]  
Belmonte N, 2017, Challenges, V8, P9, DOI [10.3390/challe8010009, 10.3390/challe8010009, DOI 10.3390/CHALLE8010009]