Facile fabrication of F-POSS star polymer coated superhydrophobic cotton fabric by successive metal-free PET-RAFT and thiol-ene click chemistry for efficient oil/water separation

被引：5
作者：
Jiang, Xiaowu [1 ]
Zhao, Bingbing [1 ]
Zhao, Meng [1 ]
Li, Shanshan [1 ]
Zhang, Guanglong [1 ]
Zhang, Zihao [1 ]
Li, Jiale [1 ]
Cai, Peng [2 ]
Ni, Lingli [1 ]
机构：
[1] Huaiyin Inst Technol, Coll Chem Engn, Key Lab Palygorskite Sci & Appl Technol Jiangsu Pr, Huaian 223003, Peoples R China
[2] Huaiyin Inst Technol, Natl & Local Joint Engn Res Ctr Deep Utilizat Tech, Huaian 223003, Peoples R China
来源：
JOURNAL OF POLYMER RESEARCH | 2023年 / 30卷 / 01期
关键词：
Oil/water separation; Superhydrophobicity; POSS; PET-RAFT; SURFACE; ROBUST; OIL; FLUOROPOLYMER; GRAPHENE; COATINGS;
D O I：
10.1007/s10965-022-03421-8
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Superhydrophobic and superhydrophilic cotton fabric was successfully fabricated by immersing commercial cotton fabric in F-POSS star polymer solutions. Herein, the well-defined fluoropolymer was firstly synthesized by EY catalyzed PET-RAFT polymerization. And then, the F-POSS star polymer was prepared by thiol-ene click chemistry. The roughness increased with the concentration of F-POSS solution. When the concentration became 15 mg/ml, the water contact angle reached 152(o), indicating the as-prepared cotton fabric present superhydrophobic. The oil/water separation performances were verified by selective adsorption, batch and continuous oil/water separations. Even after ten recycles, the separation efficiency and flux maintained over 96% and 65000 L/(m(2)& BULL;h), respectively.
引用
收藏
页数：11
相关论文
共 38 条
[1]   Superhydrophobic Metal-Organic Framework Membrane with Self-Repairing for High-Efficiency Oil/Water Emulsion Separation [J].
Cai, Yahui ;
Chen, Dongyun ;
Li, Najun ;
Xu, Qingfeng ;
Li, Hua ;
He, Jinghui ;
Lu, Jianmei .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (02) :2709-2717
[2]   Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications [J].
Chen, Mao ;
Zhong, Mingjiang ;
Johnson, Jeremiah A. .
CHEMICAL REVIEWS, 2016, 116 (17) :10167-10211
[3]   Intumescent Flame-Retardant and Self-Healing Superhydrophobic Coatings on Cotton Fabric [J].
Chen, Shanshan ;
Li, Xiang ;
Li, Yang ;
Sun, Junqi .
ACS NANO, 2015, 9 (04) :4070-4076
[4]   Superhydrophobic Graphene-Based Materials: Surface Construction and Functional Applications [J].
Chen, Zhongxin ;
Dong, Lei ;
Yang, Dong ;
Lu, Hongbin .
ADVANCED MATERIALS, 2013, 25 (37) :5352-5359
[5]   Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications [J].
Corrigan, Nathaniel ;
Jung, Kenward ;
Moad, Graeme ;
Hawker, Craig J. ;
Matyjaszewski, Krzysztof ;
Boyer, Cyrille .
PROGRESS IN POLYMER SCIENCE, 2020, 111
[6]   Laundering Durability of Superhydrophobic Cotton Fabric [J].
Deng, Bo ;
Cai, Ren ;
Yu, Yang ;
Jiang, Haiqing ;
Wang, Chunlei ;
Li, Jiang ;
Li, Linfan ;
Yu, Ming ;
Li, Jingye ;
Xie, Leidong ;
Huang, Qing ;
Fan, Chunhai .
ADVANCED MATERIALS, 2010, 22 (48) :5473-5477
[7]   Facile Preparation of Ag-Coated Superhydrophobic/Superoleophilic Mesh for Efficient Oil/Water Separation with Excellent Corrosion Resistance [J].
Du, Zhiping ;
Ding, Peng ;
Tai, Xiumei ;
Pan, Zihe ;
Yang, Hengquan .
LANGMUIR, 2018, 34 (23) :6922-6929
[8]   One-Step Transformation of Metal Meshes to Robust Superhydrophobic and Superoleophilic Meshes for Highly Efficient Oil Spill Cleanup and Oil/Water Separation [J].
Fu, Chao ;
Gu, Lin ;
Zeng, Zhixiang ;
Xue, Qunji .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (01) :1850-1857
[9]   An Oxygen-Tolerant PET-RAFT Polymerization for Screening Structure-Activity Relationships [J].
Gormley, Adam J. ;
Yeow, Jonathan ;
Ng, Gervase ;
Conway, Orla ;
Boyer, Cyrille ;
Chapman, Robert .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (06) :1557-1562
[10]   Oil/water separation techniques: a review of recent progresses and future directions [J].
Gupta, Raju Kumar ;
Dunderdale, Gary J. ;
England, Matt W. ;
Hozumi, Atsushi .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (31) :16025-16058
1234