Rhodium-catalyzed C-H selective amination of 2,4-diarylquinazolines with N-fluorobenzenesulfonimide

被引：2

作者：

Gao, Wei ^{[1
,2
]}

Hu, Lifang ^{[3
]}

Gao, Fang ^{[4
]}

Hu, Guozhu ^{[5
]}

Zhou, Xueying ^{[6
]}

机构：

[1] Jiangxi Acad Forestry, Nanchang, Peoples R China

[2] Jiangxi Normal Univ, Nanchang, Peoples R China

[3] Jiangxi Acad Agr Sci, Inst Qual & Safety & Stand Agr Prod Res, Nanchang, Peoples R China

[4] Yongfeng Cty Nat Resources Bur, Jian, Peoples R China

[5] Jiangxi Res Acad Ecol Civilizat, Nanchang, Peoples R China

[6] Dalian Med Univ, Affiliated Hosp 2, Dept Pharm, 67 Zhongshan Rd, Dalian 116023, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2024年 / 48卷 / 01期

关键词：

C-H activation; NFSI; quinazolines; rhodium catalyst; DIRECT ARYLATION; BOND FORMATION; INHIBITORS; IMIDATION; ALKENES; ARYL; 4-HYDROXYCOUMARINS; QUINAZOLINES; HETEROCYCLES; DISCOVERY;

D O I：

10.1177/17475198231226425

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rhodium-catalyzed C-H selective amination of 2,4-diarylquinazolines has been developed with the commercially available N-fluorobenzenesulfonimide as the amino source. This approach offers a unique route for direct C-H amidation and demonstrates remarkable functional group tolerance and regioselectivity.

引用

页数：8

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