The Joule-Thomson effect of (CO2+H2) binary system relevant to gas switching reforming with carbon capture and storage (CCS)

被引:12
作者
Zhang, Zhongyao [1 ]
Gao, Ming [1 ]
Chen, Xiaopeng [1 ]
Wei, Xiaojie [1 ]
Liang, Jiezhen [1 ]
Wu, Chenghong [1 ]
Wang, Linlin [1 ]
机构
[1] Guangxi Univ, Sch Chem & Chem Engn, Guangxi Key Lab Petrochem Resources Proc & Proc In, Nanning 530004, Peoples R China
来源
CHINESE JOURNAL OF CHEMICAL ENGINEERING | 2023年 / 54卷
基金
中国国家自然科学基金;
关键词
Carbon dioxide; Hydrogen; Joule-Thomson coefficient; Joule-Thomson inversion curve; GSR; CCS; EQUATION-OF-STATE; PHASE-EQUILIBRIUM; INVERSION CURVES; CUBIC EQUATIONS; ALPHA-FUNCTION; MIXTURES; HYDROGEN; DIOXIDE; COEFFICIENTS; PRESSURES;
D O I
10.1016/j.cjche.2022.03.017
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The Joule-Thomson effect is one of the important thermodynamic properties in the system relevant to gas switching reforming with carbon capture and storage (CCS). In this work, a set of apparatus was set up to determine the Joule-Thomson effect of binary mixtures (CO2 + H2). The accuracy of the apparatus was verified by comparing with the experimental data of carbon dioxide. The Joule-Thomson coefficients (lJT) for (CO2 + H2) binary mixtures with mole fractions of carbon dioxide (xCO2 = 0.1, 0.26, 0.5, 0.86, 0.94) along six isotherms at various pressures were measured. Five equations of state EOSs (PR, SRK, PR, BWR and GERG-2008 equation) were used to calculate the lJT for both pure systems and binary systems, among which the GERG-2008 predicted best with a wide range of pressure and temperature. Moreover, the Joule-Thomson inversion curves (JTIC) were calculated with five equations of state. A comparison was made between experimental data and predicted data for the inversion curve of CO2. The investigated EOSs show a similar prediction of the low-temperature branch of the JTIC for both pure and binary systems, except for the BWRS equation of state. Among all the equations, SRK has the most similar result to GERG-2008 for predicting JTIC.(c) 2022 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.
引用
收藏
页码:215 / 231
页数:17
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