High-pressure-induced phase transition and amorphization of xylitol by Raman spectroscopy

被引：1
|
作者：
Zhang, Shengya [1 ]
Fang, Wenhui [1 ,2 ,5 ]
Li, Fengjiao [3 ]
Zhao, Bo [4 ]
Men, Zhiwei [2 ,6 ]
机构：
[1] Changchun Univ Sci & Technol, Sch Sci, Changchun, Peoples R China
[2] Jilin Univ, Coll Phys, Changchun, Peoples R China
[3] Qufu Normal Univ, Sch Phys & Phys Engn, Lab High Pressure Phys & Mat Sci HPPMS, Qufu, Peoples R China
[4] Jilin Univ, State Key Lab Superhard Mat, Changchun, Peoples R China
[5] Changchun Univ Sci & Technol, Sch Sci, Changchun 130022, Peoples R China
[6] Jilin Univ, Coll Phys, Changchun 130012, Peoples R China
来源：
JOURNAL OF RAMAN SPECTROSCOPY | 2023年 / 54卷 / 03期
关键词：
amorphization; high pressure; phase transition; Raman spectroscopy; xylitol; POLYMORPHISM;
D O I：
10.1002/jrs.6481
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Creating high-pressure environments is an indispensable method to explore structural change, stability, and the upper limits for the application of xylitol under extreme conditions. Herein, we report a detailed description of the vibrations and phase transition of xylitol under high pressures by Raman spectroscopy. We found a novel phase transition of xylitol under 8.07 GPa by changing the O-H and CH2 vibrations. As the pressure further increased, xylitol underwent an amorphous transformation at 16.94 GPa. This study opens a new research perspective for polyols and expands the application of xylitol under extreme conditions.
引用
收藏
页码：333 / 339
页数：7
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