Magnesium-based energy materials: Progress, challenges, and perspectives

被引:71
作者
Han, Guang [1 ,2 ]
Lu, Yangfan [1 ,2 ,3 ,4 ]
Jia, Hongxing [1 ,2 ]
Ding, Zhao [1 ,2 ]
Wu, Liang [1 ,2 ]
Shi, Yue [1 ,2 ]
Wang, Guoyu [1 ,2 ]
Luo, Qun [5 ]
Chen, Yu'an [1 ,2 ,3 ,4 ]
Wang, Jingfeng [1 ,2 ,3 ,4 ]
Huang, Guangsheng [1 ,2 ,3 ,4 ]
Zhou, Xiaoyuan [1 ,4 ,6 ]
Li, Qian [1 ,2 ,3 ,4 ,5 ]
Pan, Fusheng [1 ,2 ,3 ,4 ]
机构
[1] Chongqing Univ, Natl Engn Res Ctr Magnesium Alloys, Chongqing 400044, Peoples R China
[2] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China
[3] Chongqing Univ, Natl Key Lab Adv Casting Technol, Chongqing 400044, Peoples R China
[4] Chongqing Inst New Energy Storage Mat & Equipment, Chongqing 401135, Peoples R China
[5] Shanghai Univ, Sch Mat Sci & Engn, State Key Lab Adv Special Steels, Shanghai Key Lab Adv Ferrometallurgy, Shanghai 200444, Peoples R China
[6] Chongqing Univ, Coll Phys, Chongqing 401331, Peoples R China
基金
中国国家自然科学基金;
关键词
Mg-based battery materials; Mg-based hydrogen storage materials; Mg-based thermoelectric materials; Composition regulation; Structure engineering; HYDROGEN STORAGE PROPERTIES; HIGH-THERMOELECTRIC PERFORMANCE; CARRIER SCATTERING MECHANISM; LATTICE THERMAL-CONDUCTIVITY; P-TYPE MG3SB2; SOLID-SOLUTIONS; ALPHA-MGAGSB; DISCHARGE PERFORMANCE; ZINTL COMPOUNDS; ELECTROCHEMICAL BEHAVIORS;
D O I
10.1016/j.jma.2023.08.009
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Magnesium-based energy materials, which combine promising energy-related functional properties with low cost, environmental com-patibility and high availability, have been regarded as fascinating candidates for sustainable energy conversion and storage. In this review, we provide a timely summary on the recent progress in three types of important Mg-based energy materials, based on the fundamental strategies of composition and structure engineering. With regard to Mg-based materials for batteries, we systematically review and analyze different material systems, structure regulation strategies as well as the relevant performance in Mg-ion batteries (MIBs) and Mg-air bat-teries (MABs), covering cathodes, electrolytes, anodes for MIBs, and anodes for MABs; as to Mg-based hydrogen storage materials, we discuss how catalyst adding, composite, alloying and nanostructuring improve the kinetic and thermodynamic properties of de/hydrogenation reactions, and in particular, the impacts of composition and structure modification on hydrogen absorption/dissociation processes and free energy modification mechanism are focused; regarding Mg-based thermoelectric materials, the relations between composition/structure and electrical/thermal transport properties of Mg3X2 (X = Sb, Bi), Mg2X (X = Si, Ge, Sn) and MgAgSb-based materials, together with the representative research progress of each material system, are summarized and discussed. Finally, by pointing out remaining challenges and providing possible solutions, this review aims to shed light on the directions and perspectives for practical applications of magnesium-based energy materials in the future. (c) 2023 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ ) Peer review under responsibility of Chongqing University
引用
收藏
页码:3896 / 3925
页数:30
相关论文
共 379 条
  • [11] Significantly enhanced thermoelectric figure of merit of p-type Mg3Sb2-based Zintl phase compounds via nanostructuring and employing high energy mechanical milling coupled with spark plasma sintering
    Bhardwaj, A.
    Chauhan, N. S.
    Misra, D. K.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (20) : 10777 - 10786
  • [12] Enhancing thermoelectric properties of a p-type Mg3Sb2- based Zintl phase compound by Pb substitution in the anionic framework
    Bhardwaj, A.
    Misra, D. K.
    [J]. RSC ADVANCES, 2014, 4 (65): : 34552 - 34560
  • [13] High-performance bulk thermoelectrics with all-scale hierarchical architectures
    Biswas, Kanishka
    He, Jiaqing
    Blum, Ivan D.
    Wu, Chun-I
    Hogan, Timothy P.
    Seidman, David N.
    Dravid, Vinayak P.
    Kanatzidis, Mercouri G.
    [J]. NATURE, 2012, 489 (7416) : 414 - 418
  • [14] Toward the Development of a High-Voltage Mg Cathode Using a Chromium Sulfide Host
    Blanc, Lauren
    Bartel, Christopher J.
    Kim, Haegyeom
    Tian, Yaosen
    Kim, Hyunchul
    Miura, Akira
    Ceder, Gerbrand
    Nazar, Linda F.
    [J]. ACS MATERIALS LETTERS, 2021, 3 (08): : 1213 - 1220
  • [15] A practical perspective on the potential of rechargeable Mg batteries
    Blazquez, J. Alberto
    Maca, Rudi R.
    Leonet, Olatz
    Azaceta, Eneko
    Mukherjee, Ayan
    Zhao-Karger, Zhirong
    Li, Zhenyou
    Kovalevsky, Aleksey
    Fernandez-Barquin, Ana
    Mainar, Aroa R.
    Jankowski, Piotr
    Rademacher, Laurin
    Dey, Sunita
    Dutton, Sian E.
    Grey, Clare P.
    Drews, Janina
    Haecker, Joachim
    Danner, Timo
    Latz, Arnulf
    Sotta, Dane
    Palacin, M. Rosa
    Martin, Jean-Frederic
    Lastra, Juan Maria Garcia
    Fichtner, Maximilian
    Kundu, Sumana
    Kraytsberg, Alexander
    Ein-Eli, Yair
    Noked, Malachi
    Aurbach, Doron
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2023, 16 (05) : 1964 - 1981
  • [16] ELECTRICAL AND OPTICAL PROPERTIES OF INTERMETALLIC COMPOUNDS .4. MAGNESIUM STANNIDE
    BLUNT, RF
    FREDERIKSE, HPR
    HOSLER, WR
    [J]. PHYSICAL REVIEW, 1955, 100 (02): : 663 - 666
  • [17] A record thermoelectric efficiency in tellurium-free modules for low-grade waste heat recovery
    Bu, Zhonglin
    Zhang, Xinyue
    Hu, Yixin
    Chen, Zhiwei
    Lin, Siqi
    Li, Wen
    Xiao, Chong
    Pei, Yanzhong
    [J]. NATURE COMMUNICATIONS, 2022, 13 (01)
  • [18] An over 10% module efficiency obtained using non-Bi2Te3 thermoelectric materials for recovering heat of <600 K
    Bu, Zhonglin
    Zhang, Xinyue
    Hu, Yixin
    Chen, Zhiwei
    Lin, Siqi
    Li, Wen
    Pei, Yanzhong
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2021, 14 (12) : 6506 - 6513
  • [19] Mechanochemical synthesis and thermoelectric properties of high quality magnesium silicide
    Bux, Sabah K.
    Yeung, Michael T.
    Toberer, Eric S.
    Snyder, G. Jeffrey
    Kaner, Richard B.
    Fleurial, Jean-Pierre
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (33) : 12259 - 12266
  • [20] Enhanced thermoelectric performance of p-type Mg3Sb2 by lithium doping and its tunability in an anionic framework
    Chen, Chen
    Li, Xiaofang
    Li, Shan
    Wang, Xinyu
    Zhang, Zongwei
    Sui, Jiehe
    Cao, Feng
    Liu, Xingjun
    Zhang, Qian
    [J]. JOURNAL OF MATERIALS SCIENCE, 2018, 53 (23) : 16001 - 16009