Enhanced fumion nanocomposite membranes embedded with graphene oxide as a promising anion exchange membrane for fuel cell application

被引:47
作者
Arunkumar, Iyappan [1 ]
Kim, Ae Rhan [1 ,2 ]
Lee, Sang Hyeok [1 ]
Yoo, Dong Jin [1 ,2 ]
机构
[1] Jeonbuk Natl Univ, Hydrogen & Fuel Cell Res Ctr, Convers Engn Grad Sch BK21 FOUR, Dept Energy Storage, Jeonju 54896, South Korea
[2] Jeonbuk Natl Univ, Dept Life Sci, Jeonju 54896, South Korea
基金
新加坡国家研究基金会;
关键词
Enhanced fumion; Anion exchange membrane; Graphene oxide; Composite membrane; Hydroxide conductivity Alkaline stability; VINYL BENZYL-CHLORIDE; STABILITY; ELECTROLYTE; PERFORMANCE; COMPOSITE; FABRICATION;
D O I
10.1016/j.ijhydene.2022.10.184
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fumion (FAA3) is a predominant anion exchange membrane/ionomer (AEM/AEI) widely used in energy storage and energy conversion applications. However, its physicochemical stability and electrochemical performance are still quite low for profitable commerciali-zation. Improving the properties of Fumion membrane via the addition of nanofillers or polymer blends is not being widely studied so far. Therefore, in this study, the Fumion membrane with different wt% of graphene oxide (GO) nanofiller was widely investigated for the fuel cell application. The obtained results indicated that water uptake, ionic con-ductivity, water contact angle, ion exchange capacity, physicochemical stability, and single-cell performance was improved by the incorporation of GO. Notably, the Fumion/GO nanocomposite membrane with 1.08 wt% of GO reached the highest ionic conductivity of 106.83 mS cm-1 at 90 degrees C, whereas the pristine Fumion exhibited ionic conductivity of only 29.19 mS cm-1. On top of that, the composite membrane achieved a maximum peak power density of 132 mW/cm2 in an alkaline H2/O2 fuel cell with robust open-circuit voltage (OCV) for 150 h. The overall study demonstrates that an appropriate amount of GO addition could result in a promising Fumion anion exchange membrane for electrolyte applications. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:139 / 153
页数:15
相关论文
共 71 条
[1]   Humidity-Dependent Surface Structure and Hydroxide Conductance of a Model Quaternary Ammonium Anion Exchange Membrane [J].
Barnes, Austin M. ;
Liu, Brendan ;
Buratto, Steven K. .
LANGMUIR, 2019, 35 (44) :14188-14193
[2]   The Control and Effect of Pore Size Distribution in AEMFC Catalyst Layers [J].
Britton, Benjamin ;
Holdcroft, Steven .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (05) :F353-F358
[3]   A quaternary ammonium grafted poly vinyl benzyl chloride membrane for alkaline anion exchange membrane water electrolysers with no-noble-metal catalysts [J].
Cao, Yuan-Cheng ;
Wu, Xu ;
Scott, Keith .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (12) :9524-9528
[4]   Poly(fluorenyl aryl piperidinium) membranes and ionomers for anion exchange membrane fuel cells [J].
Chen, Nanjun ;
Wang, Ho Hyun ;
Kim, Sun Pyo ;
Kim, Hae Min ;
Lee, Won Hee ;
Hu, Chuan ;
Bae, Joon Yong ;
Sim, Eun Seob ;
Chung, Yong-Chae ;
Jang, Jue-Hyuk ;
Yoo, Sung Jong ;
Zhuang, Yongbing ;
Lee, Young Moo .
NATURE COMMUNICATIONS, 2021, 12 (01)
[5]   Poly(Alkyl-Terphenyl Piperidinium) Ionomers and Membranes with an Outstanding Alkaline-Membrane Fuel-Cell Performance of 2.58 W cm-2 [J].
Chen, Nanjun ;
Hu, Chuan ;
Wang, Ho Hyun ;
Kim, Sun Pyo ;
Kim, Hae Min ;
Lee, Won Hee ;
Bae, Joon Yong ;
Park, Jong Hyeong ;
Lee, Young Moo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (14) :7710-7718
[6]   Highly Conducting Anion-Exchange Membranes Based on Cross-Linked Poly(norbornene): Ring Opening Metathesis Polymerization [J].
Chen, Wanting ;
Mandal, Mrinmay ;
Huang, Garrett ;
Wu, Xuemei ;
He, Gaohong ;
Kohl, Paul A. .
ACS APPLIED ENERGY MATERIALS, 2019, 2 (04) :2458-2468
[7]   Study on the Chemical Stabilities of Poly(arylene ether) Random Copolymers for Alkaline Fuel Cells: Effect of Main Chain Structures with Different Monomer Units [J].
Chu, Ji Young ;
Lee, Kyu Ha ;
Kim, Ae Rhan ;
Yoo, Dong Jin .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (24) :20077-20087
[8]   Graphene-mediated organic-inorganic composites with improved hydroxide conductivity and outstanding alkaline stability for anion exchange membranes [J].
Chu, Ji Young ;
Lee, Kyu Ha ;
Kim, Ae Rhan ;
Yoo, Dong Jin .
COMPOSITES PART B-ENGINEERING, 2019, 164 :324-332
[9]   Ionomer content optimization in nickel-iron-based anodes with and without ceria for anion exchange membrane water electrolysis [J].
Cossar, Emily ;
Barnett, Alejandro O. ;
Seland, Frode ;
Safari, Reza ;
Botton, Gianluigi A. ;
Baranova, Elena A. .
JOURNAL OF POWER SOURCES, 2021, 514
[10]   Graphene oxide-polybenzimidazolium nanocomposite anion exchange membranes for electrodialysis [J].
Cseri, Levente ;
Baugh, Joseph ;
Alabi, Adetunji ;
AlHajaj, Ahmed ;
Zou, Linda ;
Dryfe, Robert A. W. ;
Budd, Peter M. ;
Szekely, Gyorgy .
JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (48) :24728-24739