lead borosilicate glasses;
metal oxides;
phase composition;
acid-base;
redox and electrical properties;
SUBSOLIDUS PHASE-EQUILIBRIA;
ELECTRICAL-PROPERTIES;
SILICATE-GLASSES;
BURIED RESISTORS;
BORATE GLASSES;
LEAD;
CONDUCTIVITY;
PART;
D O I:
10.1134/S1087659622601101
中图分类号:
TQ174 [陶瓷工业];
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
The physicochemical processes occurring in glasses of the PbO-CdO-SiO2-B2O3-Al2O3 system after high-temperature contact with oxides of various metals-CuO, NiO, Al2O3, TiO2, Nb2O5, and WO3, as well as the electrical resistance of the obtained glasses-are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O2- ion in each specific composition.
机构:
CEA, DEN, DTCD SECM LDMC Marcoule, F-30207 Bagnols Sur Ceze, FranceCEA, DEN, DTCD SECM LDMC Marcoule, F-30207 Bagnols Sur Ceze, France
Kidari, Abdessamad
Dussossoy, Jean-Luc
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机构:
CEA, DEN, DTCD SECM LMPA Marcoule, F-30207 Bagnols Sur Ceze, FranceCEA, DEN, DTCD SECM LDMC Marcoule, F-30207 Bagnols Sur Ceze, France
Dussossoy, Jean-Luc
Brackx, Emmanuelle
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CEA, DEN, DTEC SGCS LMAC Marcoule, F-30207 Bagnols Sur Ceze, FranceCEA, DEN, DTCD SECM LDMC Marcoule, F-30207 Bagnols Sur Ceze, France
Brackx, Emmanuelle
Caurant, Daniel
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机构:
Ecole Natl Super Chim Paris Chim ParisTech, CNRS, UMR 7574, Lab Chim Matiere Condensee Paris, Paris, FranceCEA, DEN, DTCD SECM LDMC Marcoule, F-30207 Bagnols Sur Ceze, France
Caurant, Daniel
Magnin, Magali
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CEA, DEN, DTCD SECM LMPA Marcoule, F-30207 Bagnols Sur Ceze, FranceCEA, DEN, DTCD SECM LDMC Marcoule, F-30207 Bagnols Sur Ceze, France
Magnin, Magali
Bardez-Giboire, Isabelle
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机构:
CEA, DEN, DTCD SECM LDMC Marcoule, F-30207 Bagnols Sur Ceze, FranceCEA, DEN, DTCD SECM LDMC Marcoule, F-30207 Bagnols Sur Ceze, France
机构:
Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China
Chongqing Univ, Chongqing Key Lab Vanadium Titanium Met & New Mat, Chongqing 400044, Peoples R ChinaChongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China
Lai, Feifei
Yao, Wen
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机构:
Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China
Chongqing Univ, Chongqing Key Lab Vanadium Titanium Met & New Mat, Chongqing 400044, Peoples R ChinaChongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China
Yao, Wen
Li, Jiangling
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机构:
Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China
Chongqing Univ, Chongqing Key Lab Vanadium Titanium Met & New Mat, Chongqing 400044, Peoples R ChinaChongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China
机构:
Stockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, Div Phys Chem, SE-10691 Stockholm, SwedenStockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, Div Phys Chem, SE-10691 Stockholm, Sweden
Iftekhar, Shahriar
Grins, Jekabs
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机构:
Stockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, Inorgan Chem Div, SE-10691 Stockholm, SwedenStockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, Div Phys Chem, SE-10691 Stockholm, Sweden
Grins, Jekabs
Eden, Mattias
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机构:
Stockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, Div Phys Chem, SE-10691 Stockholm, SwedenStockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, Div Phys Chem, SE-10691 Stockholm, Sweden