Effect of Oxides of Various Metals on the Physicochemical Properties of Glass in the PbO-CdO-SiO2-B2O3-Al2O3 System

被引:1
|
作者
Lozinskii, N. S. [1 ]
Moroz, Ya. A. [1 ]
Lopanov, A. N. [2 ]
机构
[1] Litvinenko Inst Phys Organ Chem & Coal Chem, Doneck 283114, Russia
[2] Shukhov Belgorod State Technol Univ, Belgorod 308012, Russia
关键词
lead borosilicate glasses; metal oxides; phase composition; acid-base; redox and electrical properties; SUBSOLIDUS PHASE-EQUILIBRIA; ELECTRICAL-PROPERTIES; SILICATE-GLASSES; BURIED RESISTORS; BORATE GLASSES; LEAD; CONDUCTIVITY; PART;
D O I
10.1134/S1087659622601101
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The physicochemical processes occurring in glasses of the PbO-CdO-SiO2-B2O3-Al2O3 system after high-temperature contact with oxides of various metals-CuO, NiO, Al2O3, TiO2, Nb2O5, and WO3, as well as the electrical resistance of the obtained glasses-are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O2- ion in each specific composition.
引用
收藏
页码:136 / 149
页数:14
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