Microscopic and macroscopic structural strategies for enhancing microwave absorption in MXene-Based composites

被引:20
|
作者
Zhao, Zehao [1 ]
Shi, Bin [1 ,2 ]
Wang, Tao [1 ]
Wang, Rumin [1 ]
Chang, Qing [1 ,2 ]
Yun, Jijun [1 ]
Zhang, Limin [1 ]
Wu, Hongjing [1 ]
机构
[1] Northwestern Polytech Univ, MOE Key Lab Mat Phys & Chem Extraordinary, Xian 710072, Peoples R China
[2] Yanan Univ, Coll Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Peoples R China
基金
美国国家科学基金会;
关键词
MXene; Microwave absorption; Microstructure; Macrostructure; ELECTROMAGNETIC-WAVE ABSORPTION; TI3C2TX MXENE; RECENT PROGRESS; PERFORMANCE; HYBRIDS; FOAM; DESIGN; FIBER; FILMS; LIGHT;
D O I
10.1016/j.carbon.2023.118450
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Microwave absorption materials (MAMs) play a crucial role in mitigating electromagnetic pollution and enhancing communication technology. MXenes, a family of two-dimensional materials, have emerged as promising candidates for MAMs due to their unique layered structure, large surface area, abundant defects, and high electrical conductivity. However, the poor impedance matching of MXene poses a challenge for effective absorption. This review comprehensively discusses strategies for optimizing MXene-based MAMs through microstructure and macrostructure design. In two-dimensional microstructures, strong absorption is primarily achieved by self-transformation MXene and introducing other components to expand layer spacing and enhance dielectric/magnetic losses. In 3D microstructures, MXene serves as a framework and additive to create diverse geometrical frameworks such as porous, hollow, and hierarchical structures, optimizing electromagnetic properties. Additionally, MXene-based aerogels, foams, and films developed through 3D macrostructural design offer greater flexibility for performance tuning and multifunctional design. Therefore, this review may provide guidance for the structural design of MXene-based MAMs.
引用
收藏
页数:23
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