Coordinatively Cross-Linked Binders for Silicon-Based Electrodes for Li-Ion Batteries: Beneficial Impact on Mechanical Properties and Electrochemical Performance
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作者:
Huet, Lucas
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Nantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Inst Natl Rech Sci INRS, Ctr Energie, Mat, Telecommun EMT, Varennes, PQ J3X 1S2, CanadaNantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Huet, Lucas
[1
,2
]
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Mazouzi, Driss
[3
]
Moreau, Philippe
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Nantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, FranceNantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Moreau, Philippe
[1
]
Dupre, Nicolas
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Nantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, FranceNantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Dupre, Nicolas
[1
]
Paris, Michael
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Nantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, FranceNantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Paris, Michael
[1
]
Mittelette, Sebastien
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Univ Montpellier, CNRS, ICGM, ENSCM, F-34095 Montpellier, FranceNantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Mittelette, Sebastien
[4
]
Laurencin, Danielle
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Univ Montpellier, CNRS, ICGM, ENSCM, F-34095 Montpellier, FranceNantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Laurencin, Danielle
[4
]
Devic, Thomas
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Nantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, FranceNantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Devic, Thomas
[1
]
Roue, Lionel
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Inst Natl Rech Sci INRS, Ctr Energie, Mat, Telecommun EMT, Varennes, PQ J3X 1S2, CanadaNantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
Roue, Lionel
[2
]
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Lestriez, Bernard
[1
]
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[1] Nantes Univ, CNRS, Inst Mat Nantes Jean Rouxel, IMN, F-44000 Nantes, France
A simple and versatile preparation of Zn(II)-poly(carboxylates) reticulated binders by the addition of Zn(II) precursors (ZnSO4, ZnO, or Zn(NO3)2) into a preoptimized poly(carboxylic acids) binder solution is proposed. These binders lead systematically to a significantly improved electrochemical performance when used for the formulation of silicon-based negative electrodes. The formation of carboxylate-Zn(II) coordination bonds formation is investigated by rheology and FTIR and NMR spectroscopies. Mechanical characterizations reveal that the coordinated binder offers a better electrode coating cohesion and adhesion to the current collector, as well as higher hardness and elastic modulus, which are even preserved in the presence of a carbonate solvent (i.e., in battery operation conditions). Ultimately, as shown from operando dilatometry experiments, the electrode expansion during lithiation is reduced, mitigating electrode mechanical failure. Such coordinatively reticulated electrodes outperform their uncoordinated counterparts with an improved capacity retention of over 30% after 60 cycles.
机构:
PSL Res Univ, MINES ParisTech, Ctr Mise Forme Mat CEMEF, CNRS UMR 7635, CS 10207,Rue Claude Daunesse, F-06904 Sophia Antipolis, FrancePSL Res Univ, MINES ParisTech, Ctr Mise Forme Mat CEMEF, CNRS UMR 7635, CS 10207,Rue Claude Daunesse, F-06904 Sophia Antipolis, France
Budtova, Tatiana
Navard, Patrick
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PSL Res Univ, MINES ParisTech, Ctr Mise Forme Mat CEMEF, CNRS UMR 7635, CS 10207,Rue Claude Daunesse, F-06904 Sophia Antipolis, FrancePSL Res Univ, MINES ParisTech, Ctr Mise Forme Mat CEMEF, CNRS UMR 7635, CS 10207,Rue Claude Daunesse, F-06904 Sophia Antipolis, France
机构:
Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
Chandrasiri, K. W. D. Kaveendi
Nguyen, Cao Cuong
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h-index: 0
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Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
Nguyen, Cao Cuong
Parimalam, Bharathy S.
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Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
Parimalam, Bharathy S.
Jurng, Sunhyung
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Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
Jurng, Sunhyung
Lucht, Brett L.
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Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
机构:
China Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Chen, Zhou
Zhang, Huanrui
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Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Zhang, Huanrui
Dong, Tiantian
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Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Dong, Tiantian
Mu, Pengzhou
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Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Mu, Pengzhou
Rong, Xianchao
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China Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Rong, Xianchao
Li, Zhongtao
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China Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
机构:
Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Umicore Grp Res & Dev, Olen, BelgiumUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Delpuech, N.
Mazouzi, D.
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Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Mazouzi, D.
Dupre, N.
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Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Dupre, N.
Moreau, P.
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Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Moreau, P.
Cerbelaud, M.
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Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Cerbelaud, M.
Bridel, J. S.
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Umicore Grp Res & Dev, Olen, BelgiumUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Bridel, J. S.
Badot, J. -C.
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Univ Paris 06, CNRS, Chim ParisTech, Lab Chim Matiere Condensee Paris, Paris, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Badot, J. -C.
De Vito, E.
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CEA Grenoble, LITEN, Nanocharacterizat Ctr, F-38054 Grenoble, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
De Vito, E.
Guyomard, D.
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Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
机构:
PSL Res Univ, MINES ParisTech, Ctr Mise Forme Mat CEMEF, CNRS UMR 7635, CS 10207,Rue Claude Daunesse, F-06904 Sophia Antipolis, FrancePSL Res Univ, MINES ParisTech, Ctr Mise Forme Mat CEMEF, CNRS UMR 7635, CS 10207,Rue Claude Daunesse, F-06904 Sophia Antipolis, France
Budtova, Tatiana
Navard, Patrick
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h-index: 0
机构:
PSL Res Univ, MINES ParisTech, Ctr Mise Forme Mat CEMEF, CNRS UMR 7635, CS 10207,Rue Claude Daunesse, F-06904 Sophia Antipolis, FrancePSL Res Univ, MINES ParisTech, Ctr Mise Forme Mat CEMEF, CNRS UMR 7635, CS 10207,Rue Claude Daunesse, F-06904 Sophia Antipolis, France
机构:
Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
Chandrasiri, K. W. D. Kaveendi
Nguyen, Cao Cuong
论文数: 0引用数: 0
h-index: 0
机构:
Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
Nguyen, Cao Cuong
Parimalam, Bharathy S.
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h-index: 0
机构:
Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
Parimalam, Bharathy S.
Jurng, Sunhyung
论文数: 0引用数: 0
h-index: 0
机构:
Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
Jurng, Sunhyung
Lucht, Brett L.
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h-index: 0
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Univ Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USAUniv Rhode Isl, Richard E Beaupre Ctr Chem & Forens Sci, Kingston, RI 02881 USA
机构:
China Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Chen, Zhou
Zhang, Huanrui
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Zhang, Huanrui
Dong, Tiantian
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h-index: 0
机构:
Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Dong, Tiantian
Mu, Pengzhou
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h-index: 0
机构:
Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Mu, Pengzhou
Rong, Xianchao
论文数: 0引用数: 0
h-index: 0
机构:
China Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
Rong, Xianchao
Li, Zhongtao
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h-index: 0
机构:
China Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R ChinaChina Univ Petr East China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
机构:
Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Umicore Grp Res & Dev, Olen, BelgiumUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Delpuech, N.
Mazouzi, D.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Mazouzi, D.
Dupre, N.
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h-index: 0
机构:
Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Dupre, N.
Moreau, P.
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h-index: 0
机构:
Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Moreau, P.
Cerbelaud, M.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Cerbelaud, M.
Bridel, J. S.
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h-index: 0
机构:
Umicore Grp Res & Dev, Olen, BelgiumUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Bridel, J. S.
Badot, J. -C.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Paris 06, CNRS, Chim ParisTech, Lab Chim Matiere Condensee Paris, Paris, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
Badot, J. -C.
De Vito, E.
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h-index: 0
机构:
CEA Grenoble, LITEN, Nanocharacterizat Ctr, F-38054 Grenoble, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
De Vito, E.
Guyomard, D.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France
FR CNRS, Reseau Stockage Electrochim Energie RS2E, F-3459 Nantes, FranceUniv Nantes, CNRS, Inst Mat Jean Rouxel IMN, Nantes, France