Versatile Synthesis of Hollow-Structured Mesoporous Carbons by Enhanced Surface Interaction for High-Performance Lithium-Ion Batteries

被引:21
作者
Liang, Zhenjin [1 ]
Peng, Yuhao [1 ,2 ]
Feng, Huanhuan [1 ]
Hong, Zibo [1 ]
Liu, Fengqing [3 ]
Yu, Ruohan [4 ]
Cao, Yue [1 ]
Xie, Mingyue [1 ]
Zhang, Yuanteng [1 ]
Zhang, Xing [1 ]
Yi, Xianfeng [3 ]
Zheng, Anmin [3 ]
Wu, Jinsong [4 ]
Xiao, Wei [2 ]
Schueth, Ferdi [5 ]
Gu, Dong [1 ]
机构
[1] Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Coll Chem & Mol Sci, Hubei Key Lab Electrochem Power Sources, Wuhan 430072, Peoples R China
[3] Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Natl Ctr Magnet Resonance Wuhan, Wuhan Inst Phys & Math,Innovat Acad Precis Measure, Wuhan 430071, Peoples R China
[4] Wuhan Univ Technol, Nanostruct Res Ctr NRC, Wuhan 430070, Peoples R China
[5] Max Planck Inst Kohlenforsch, Kaiser Wilhelm Pl 1, D-45470 Mulheim, Germany
基金
国家重点研发计划;
关键词
hollow structures; lithium-ion batteries; mesoporous carbon; silanol group; surface-casting; METAL-OXIDES; NANOSPHERES; PRELITHIATION; CONVERSION; NANOTUBES; STRATEGY; SPHERES; SILICA; ANODES; ARRAYS;
D O I
10.1002/adma.202305050
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanoporous carbons are very attractive for various applications including energy storage. Templating methods with assembled amphiphilic molecules or porous inorganic templates are typically used for the synthesis. Amongst the different members of this family, CMK-5-like structures that are constructed to consist of sub-10 nm amorphous carbon nanotubes and ultrahigh specific surface area due to their thin pore walls, have the best properties in various respects. However, the fabrication of such hollow-structured mesoporous carbons entails elaborately tailoring the surface properties of the template pore walls and selecting specific carbon precursors. Thus, very limited cases are successful. Herein, a versatile and general silanol-assisted surface-casting method to create hollow-structured mesoporous carbons and heteroatom-doped derivatives with numerous organic molecules (e.g., furfuryl alcohol, resol, 2-thiophene methanol, dopamine, tyrosine) and different structural templates is reported. These carbon materials exhibit ultrahigh surface area (2400 m2 g-1), large pore volume (4.0 cm3 g-1), as well as satisfactory lithium-storage capacity (1460 mAh g-1 at 0.1 A g-1), excellent rate capability (320 mAh g-1 at 5 A g-1), and very outstanding cycling performance (2000 cycles at 5 A g-1). Hollow-structured mesoporous carbons with ultrahigh surface area, large pore volume and heteroatom doping are synthesized by a versatile and general silanol-assisted surface-casting method. The materials display remarkable electrochemical performance for lithium-ion batteries. The studies reveal that strong interactions between the organic molecules and the silanol-rich surface of the silica template are crucial.image
引用
收藏
页数:11
相关论文
共 72 条
[41]   Nitrogen-Doped Porous Carbon Nanofiber Webs as Anodes for Lithium Ion Batteries with a Superhigh Capacity and Rate Capability [J].
Qie, Long ;
Chen, Wei-Min ;
Wang, Zhao-Hui ;
Shao, Qing-Guo ;
Li, Xiang ;
Yuan, Li-Xia ;
Hu, Xian-Luo ;
Zhang, Wu-Xing ;
Huang, Yun-Hui .
ADVANCED MATERIALS, 2012, 24 (15) :2047-2050
[42]   Engineering Peculiar Cathode Electrolyte Interphase toward Sustainable and High-Rate Li-S Batteries [J].
Qiu, Chang-Ding ;
Hu, Youcheng ;
Cao, Kewei ;
Wu, Xiangjiang ;
Huang, Bi-Hong ;
Liu, Jin ;
Wang, Yun-Xiao ;
Luo, Laibing ;
Gu, Dong ;
Ai, Xinping ;
Cao, Yuliang ;
Chen, Shengli ;
Ke, Fu-Sheng .
ADVANCED ENERGY MATERIALS, 2023, 13 (19)
[43]   Calculation of XRD patterns of simulated FDU-15, CMK-5, and CMK-3 carbon structures [J].
Schmidt, Wolfgang .
MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 117 (1-2) :372-379
[44]   Hierarchical porous carbon nanosheets and their favorable high-rate performance in lithium ion batteries [J].
Song, Ranran ;
Song, Huaihe ;
Zhou, Jisheng ;
Chen, Xiaohong ;
Wu, Bin ;
Yang, Hui Ying .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (24) :12369-12374
[45]   Structural characterization of Nigerian coals by X-ray diffraction, Raman and FTIR spectroscopy [J].
Sonibare, Oluwadayo O. ;
Haeger, Tobias ;
Foley, Stephen F. .
ENERGY, 2010, 35 (12) :5347-5353
[46]   Nitrogen-doped hollow carbon spheres with large mesoporous shells engineered from diblock copolymer micelles [J].
Tang, Jing ;
Liu, Jian ;
Salunkhe, Rahul R. ;
Wang, Tao ;
Yamauchi, Yusuke .
CHEMICAL COMMUNICATIONS, 2016, 52 (03) :505-508
[47]   Hollow Carbon Nanospheres with Superior Rate Capability for Sodium-Based Batteries [J].
Tang, Kun ;
Fu, Lijun ;
White, Robin J. ;
Yu, Linghui ;
Titirici, Maria-Magdalena ;
Antonietti, Markus ;
Maier, Joachim .
ADVANCED ENERGY MATERIALS, 2012, 2 (07) :873-877
[48]   Nanoengineering Carbon Spheres as Nanoreactors for Sustainable Energy Applications [J].
Tian, Hao ;
Liang, Ji ;
Liu, Jian .
ADVANCED MATERIALS, 2019, 31 (50)
[49]   Prelithiation: A Crucial Strategy for Boosting the Practical Application of Next-Generation Lithium Ion Battery [J].
Wang, Fei ;
Wang, Bo ;
Li, Jingxuan ;
Wang, Bin ;
Zhou, Yu ;
Wang, Dianlong ;
Liu, Huakun ;
Dou, Shixue .
ACS NANO, 2021, 15 (02) :2197-2218
[50]   Pseudocapacitive contributions to electrochemical energy storage in TiO2 (anatase) nanoparticles [J].
Wang, John ;
Polleux, Julien ;
Lim, James ;
Dunn, Bruce .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (40) :14925-14931