Induced CPL-Active Materials Based on Chiral Supramolecular Co-Assemblies

被引:0
|
作者
Zhang, Yuxia
Yu, Wenting
Li, Hang
Zheng, Wenhua
Cheng, Yixiang
机构
[1] Nanjing University, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing
[2] Nanjing University of Posts and Telecommunications, Key Laboratory for Organic Electronics &, Information Displays (KLOEID) and, Institute of Advanced Materials, National Synergistic Innovation Center for, Advanced Materials (SICAM), Nanjing
基金
中国国家自然科学基金;
关键词
chiral supramolecular assembly; chirality induction; chirality transfer; circularly polarized luminescence; CPL amplification effect;
D O I
10.1002/chem.202382262
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Circularly polarized luminescence (CPL) has attracted much interest due to its potential applications on chiral photonic techniques and optoelectronic materials science. As known, dissymmetry factor (g(em)) of CPL is one essential factor for evaluating the features of CPL-active materials. Much attention has focused on how to increase the g(em) value, which is one of the most important issues for CPL practical applications. Recently, more and more works have demonstrated that chiral supramolecular could provide the significant strategy to improve the g(em) value through the orderly helical superstructure of chiral building blocks. Normally, this kind of chiral supramolecular assembly process can be accompanied by chirality transfer and induction mechanism, which can promote the amplification effect on the induced CPL of achiral dyes. In this review, we fully summarized recent advances on the induced CPL-active materials of chiral supramolecular co-assemblies, their applications in circularly polarized organic light-emitting diodes (CP-OLEDs) and current challenges.
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页数:1
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