Micro-cones Cu fabricated by pulse electrodeposition for solderless Cu-Cu direct bonding

被引:8
作者
Zhang, Minghui [1 ,2 ]
Gao, Li-Yin [2 ,3 ]
Wang, Yu-Xi [2 ]
Dong, Wei [1 ]
Zhao, Ning [1 ]
Liu, Zhi-Quan [1 ,2 ,3 ]
机构
[1] Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
[2] Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen Inst Adv Elect Mat, Shenzhen 518055, Peoples R China
[3] Univ Chinese Acad Sci, Shenzhen Coll Adv Technol, Shenzhen 518055, Peoples R China
基金
中国国家自然科学基金;
关键词
Micro-cones Cu; Cu-Cu direct bonding; Plastic deformation; Microstructure; Bonding mechanism; DEFORMATION; FILMS;
D O I
10.1016/j.apsusc.2023.159184
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the post-Moore's era, Cu-Cu direct bonding has garnered significant attention as a promising alternative to solder joints for chip interconnection in advanced electronic packaging technology. Its advantages lie in reduced process restrictions and steps, as well as lower bonding temperature, which align with the demands for low cost and high compatibility. In this study, (1 1 0)-oriented micro-cones Cu was fabricated via template-free pulse electrodeposition, enabling solderless Cu-Cu direct bonding at 250 degrees C under three distinct bonding pressures without chemical mechanical polishing (CMP). The contact bonding area and shear strength gradually increased corresponding to the applied bonding pressure. Seamless bonding interface was achieved under high bonding pressure, leading to high shear strength of 116.4 MPa for Cu-Cu bonding joints. The obtuse polygon pyramid micro-cones, characterized by an enlarging cross-sectional area from apex to base, coupled with inherent mechanical properties, induce high applied stress at micro-cone's tip and a low yield stress, facilitating the initiation and propagation of plastic deformation during the bonding process. This study has demonstrated the feasibility of utilizing the micro-cones Cu for low-temperature bonding without CMP treatment, offering valuable insights into the advanced interconnection technologies.
引用
收藏
页数:9
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共 30 条
[1]   The future transistors [J].
Cao, Wei ;
Bu, Huiming ;
Vinet, Maud ;
Cao, Min ;
Takagi, Shinichi ;
Hwang, Sungwoo ;
Ghani, Tahir ;
Banerjee, Kaustav .
NATURE, 2023, 620 (7974) :501-515
[2]   Deformation twinning in nanocrystalline aluminum [J].
Chen, MW ;
Ma, E ;
Hemker, KJ ;
Sheng, HW ;
Wang, YM ;
Cheng, XM .
SCIENCE, 2003, 300 (5623) :1275-1277
[3]   Temperature Gradient Induced Orientation Change of Bi Grains in Sn-Bi57-Ag0.7 Solder Joint [J].
Chen, Yinbo ;
Gao, Zhaoqing ;
Liu, Zhi-Quan .
ACTA METALLURGICA SINICA-ENGLISH LETTERS, 2022, 35 (07) :1184-1194
[4]   Investigation of Pillar-Concave Structure for Low-Temperature Cu-Cu Direct Bonding in 3-D/2.5-D Heterogeneous Integration [J].
Chou, Tzu-Chieh ;
Yang, Kai-Ming ;
Li, Jian-Chen ;
Yu, Ting-Yang ;
Yang, Yu-Tao ;
Hu, Han-Wen ;
Liu, Yu-Wei ;
Ko, Cheng-Ta ;
Chen, Yu-Hua ;
Tseng, Tzyy-Jang ;
Chen, Kuan-Neng .
IEEE TRANSACTIONS ON COMPONENTS PACKAGING AND MANUFACTURING TECHNOLOGY, 2020, 10 (08) :1296-1303
[5]   Highly textured and twinned Cu films fabricated by pulsed electrodeposition [J].
Cui, B. Z. ;
Han, K. ;
Xin, Y. ;
Waryoba, D. R. ;
Mbaruku, A. L. .
ACTA MATERIALIA, 2007, 55 (13) :4429-4438
[6]   Nanotwinned copper micro-cone array fabricated by pulse electrodeposition for low-temperature bonding [J].
Dong, Mengya ;
Chen, Peixin ;
Hang, Tao ;
Li, Ming .
MATERIALS LETTERS, 2021, 290
[7]   Effect of microstructure on plastic deformation of Cu at low homologous temperatures [J].
Estrin, Y. ;
Isaev, N. V. ;
Lubenets, S. V. ;
Malykhin, S. V. ;
Pugachov, A. T. ;
Pustovalov, V. V. ;
Reshetnyak, E. N. ;
Fomenko, V. S. ;
Fomenko, L. S. ;
Shumilin, S. E. ;
Janecek, M. ;
Hellmig, R. J. .
ACTA MATERIALIA, 2006, 54 (20) :5581-5590
[8]   Interfacial morphologies and possible mechanisms of a novel low temperature insertion bonding technology based on micro-nano cones array [J].
Geng, Wenyan ;
Chen, Zhuo ;
Hu, Anmin ;
Li, Ming .
MATERIALS LETTERS, 2012, 78 :72-74
[9]   Combined effects of crystallographic orientation, stacking fault energy and grain size on deformation twinning in fcc crystals [J].
Han, W. Z. ;
Zhang, Z. F. ;
Wu, S. D. ;
Li, S. X. .
PHILOSOPHICAL MAGAZINE, 2008, 88 (24) :3011-3029
[10]   Effects of Ni-W(Au) coated Cu microcones on the bonding interfaces [J].
Hu, Fengtian ;
Wang, Haozhe ;
Yang, Shan ;
Hu, Anmin ;
Li, Ming .
APPLIED SURFACE SCIENCE, 2015, 353 :774-780