Binaphthyl-Based Chiral Macrocyclic Hosts for the Selective Recognition of Iodide Anions

被引：2

作者：

Wang, Zong-Cheng ^{[1
]}

Tan, Ying-Zi ^{[1
]}

Tang, Lin-Li ^{[1
]}

Zeng, Fei ^{[1
]}

机构：

[1] Hunan Univ Sci & Engn, Dept Biol & Chem, Yongzhou 415199, Peoples R China

来源：

MOLECULES | 2023年 / 28卷 / 12期

基金：

中国国家自然科学基金;

关键词：

binaphthyl; chiral macrocyclic; iodide anion; recognition; supramolecular chemistry; BINDING; WATER; BENZENE; COMPLEXES; RECEPTOR; CL;

D O I：

10.3390/molecules28124784

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

In this study, we explorethe synthesis of binaphthyl-based chiral macrocyclic hosts for the first time. They exhibited the selective recognition abilities of iodide anions which can be favored over those of other anions (AcO-, NO3-, ClO4-, HSO4-, Br-, PF6-, H2PO4-, BF4-, and CO3F3S-), as confirmed by UV-vis, HRMS, and H-1 NMR spectroscopy experiments, as well as DFT calculations. Neutral aryl C-H & BULL;& BULL;& BULL;anion interactions play an important role in the formation complexes. The recognition process can be observed by the naked eye.

引用

页数：9

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