Synthesis and Structures of Lead(II) Complexes with Hydroxy-Substituted Closo-Decaborate Anions

被引：7

作者：

Matveev, Evgenii Yu. ^{[1
,2
]}

Avdeeva, Varvara V. ^{[2
]}

Kubasov, Alexey S. ^{[2
]}

Zhizhin, Konstantin Yu. ^{[2
]}

Malinina, Elena A. ^{[2
]}

Kuznetsov, Nikolay T. ^{[2
]}

机构：

[1] Russian Technol Univ, Inst Fine Chem Technol Named M V Lomonosov, MIREA, Vernadskogo pr 86, Moscow 119571, Russia

[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii pr 31, Moscow 119991, Russia

来源：

INORGANICS | 2023年 / 11卷 / 04期

关键词：

boron cluster anions; decahydro-closo-decaborate anion; decahydrido-closo-decaborate anion; complexes; lead; non-covalent interactions; POLYHEDRAL BORON HYDRIDES; NICKEL(II) COMPLEXES; BUILDING-BLOCKS; DODECABORATE; DERIVATIVES; AROMATICITY; ACTIVATION; BORANES; SILVER; LIPIDS;

D O I：

10.3390/inorganics11040144

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed-ligand lead(II) complexes with 2,2 '-bipyridyl and [B10H9OH](2-) or monosubstituted hydroxy-substituted closo-decaborate anions with a pendant hydroxy group, separated from the boron cage by an alkoxylic spacer of different lengths [B10H9O(CH2)(x)O(CH2)(2)OH]](2-) (x = 2 or 5) have been synthesized. Compounds have been characterized by IR and multinuclear NMR spectroscopies. The structures of binuclear complex [Pb(bipy)(2)[B10H9OH]](2)Greek ano teleiaCH(3)CN (1Greek ano teleiaCH(3)CN), mononuclear complex [Pb(bipy)(2)[B10H9O(CH2)(2)O(CH2)(2)OH]]Greek ano teleia0.5bipyGreek ano teleiaCH(3)CN (2Greek ano teleia0.5bipyGreek ano teleiaCH(3)CN), and polymeric complex [Pb(bipy)[B10H9O(CH2)(5)O(CH2)(2)OH]](n) (3) have been determined by single-crystal X-ray diffraction. In all three compounds, the co-ordination polyhedra of lead(II) are formed by N atoms from two bipy molecules, O atoms of the substituent attached to the boron cage, and BH groups of the boron cage.

引用

页数：15

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