Self-Assembly of Block Copolymers in Thin Films Swollen-Rich in Solvent Vapors

被引：5

作者：

Babutan, Iulia ^{[1
,2
]}

Todor-Boer, Otto ^{[3
]}

Atanase, Leonard Ionut ^{[4
,5
]}

Vulpoi, Adriana ^{[1
]}

Botiz, Ioan ^{[1
,2
]}

机构：

[1] Babes Bolyai Univ, Interdisciplinary Res Inst Bionanosci, Cluj Napoca 400271, Romania

[2] Babes Bolyai Univ, Fac Phys, Cluj Napoca 400084, Romania

[3] Res Inst Analyt Instrumentat, INCDO INOE 2000, Cluj Napoca 400293, Romania

[4] Apollonia Univ Iasi, Fac Med Dent, Dept Biomat, Iasi 700511, Romania

[5] Acad Romanian Scientists, Bucharest 050045, Romania

来源：

POLYMERS | 2023年 / 15卷 / 08期

关键词：

block copolymers; thin films; solvent vapor annealing; self-assembly; atomic force microscopy; STRUCTURE-PROPERTY CORRELATIONS; DIBLOCK COPOLYMERS; EMISSION PROPERTIES; POLYMERS; MICELLIZATION; NANOPARTICLES; POLYSTYRENE; MICELLES; BEHAVIOR;

D O I：

10.3390/polym15081900

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this study we have employed a polymer processing method based on solvent vapor annealing in order to condense relatively large amounts of solvent vapors onto thin films of block copolymers and thus to promote their self-assembly into ordered nanostructures. As revealed by the atomic force microscopy, a periodic lamellar morphology of poly(2-vinylpyridine)-b-polybutadiene and an ordered morphology comprised of hexagonally-packed structures made of poly(2-vinylpyridine)-b-poly(cyclohexyl methacrylate) were both successfully generated on solid substrates for the first time.

引用

页数：13

共 50 条

[1] Morphological Characteristics of Biopolymer Thin Films Swollen-Rich in Solvent Vapors
Babutan, Mihai
Botiz, Ioan
BIOMIMETICS, 2024, 9 (07)
[2] Crystallization of Poly(ethylene oxide)-Based Triblock Copolymers in Films Swollen-Rich in Solvent Vapors
Babutan, Iulia
Todor-Boer, Otto
Atanase, Leonard Ionut
Vulpoi, Adriana
Botiz, Ioan
COATINGS, 2023, 13 (05)
[3] Self-assembly of block copolymers in thin films
Matsen, MW
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 1998, 3 (01) : 40 - 47
[4] On the Self-Assembly of Brush Block Copolymers in Thin Films
Hong, Sung Woo
Gu, Weiyin
Huh, June
Sveinbjornsson, Benjamin R.
Jeong, Gajin
Grubbs, Robert Howard
Russell, Thomas P.
ACS NANO, 2013, 7 (11) : 9684 - 9692
[5] Tunable and rapid self-assembly of block copolymers using mixed solvent vapors
Park, Woon Ik
Tong, Sheng
Liu, Yuzi
Jung, Il Woong
Roelofs, Andreas
Hong, Seungbum
NANOSCALE, 2014, 6 (24) : 15216 - 15221
[6] Nanostructured thin films via self-assembly of block copolymers
Krausch, G
Magerle, R
ADVANCED MATERIALS, 2002, 14 (21) : 1579 - +
[7] Surface modifying copolymers for self-assembly of block copolymers in thin-films
Han, Eungnak
Kim, Myungwoong
Kim, Yun Jun
Safron, Nathaniel S.
Arnold, Michael S.
Gopalan, Padma
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[8] Self-assembly of metallo-supramolecular block copolymers in thin films
Fustin, Charles-Andre
Guillet, Pierre
Misner, Matthew J.
Russell, Thomas P.
Schubert, Ulrich S.
Gohy, Jean-Franicois
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (14) : 4719 - 4724
[9] Solvent-assisted self-assembly of block copolymer thin films
Pula, Przemyslaw
Leniart, Arkadiusz
Majewski, Pawel W.
SOFT MATTER, 2022, 18 (21) : 4042 - 4066
[10] Ordering and nanoscale self-assembly of thin films of mesogenic block copolymers.
Hammond, PT
Anthamatten, M
Wu, JS
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U556 - U556

← 1 2 3 4 5 →