Steam Regeneration of Exhausted Activated Carbon Used in Natural Gas Dehydration by a Triethylene Glycol Unit

被引:0
作者
Djamila, B. [1 ]
Allali, A. [1 ,2 ]
Youcef, B. [1 ]
Sellami, M. H. [3 ]
机构
[1] Univ Amar Telidji Laghouat, Fac Technol, Dept Proc Engn, BP 37G,Route Ghardaia, Laghouat 03000, Algeria
[2] Sonatrach, Oil & Gas Explorat & Serv, Hassi Messaoud, Ouargla, Algeria
[3] Kasdi Merbah Univ, Proc Engn Lab PEL, Ouargla 30000, Algeria
来源
PHYSICAL CHEMISTRY RESEARCH | 2024年 / 12卷 / 01期
关键词
Steam regeneration; Exhausted activated carbon; Iodine number; Triethylene glycol; Regeneration efficiency; THERMAL REGENERATION; ADSORPTION-KINETICS; PROCESS PARAMETERS; OPTIMIZATION; DYE; DESORPTION; REMOVAL; BEDS;
D O I
10.22036/pcr.2023.385578.2287
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This study investigated the optimization of the regeneration of exhausted activated carbon (EAC) by hydrocarbons used in natural gas dehydration plants. For this purpose, various methods, including chemical, thermal, and steam regeneration, were used. The experimental results demonstrated the effectiveness of the steam regeneration of EAC at low temperatures, which was further enhanced by the preregeneration of EAC with dilute acid (2.5% hydrochloric acid). In addition, the performance of regenerated activated carbon (RAC) against hydrocarbons, prepared from exhausted triethylene glycol (ETEG), was evaluated using the following three parameters: the iodine number in EAC, the refractive index, and the density of TEG regenerated for determining the adsorption capacity. The results showed that the adsorption capacity of RAC on hydrocarbons from ETEG increased with increasing temperature, resulting in highly pure, hydrocarbon-free TEG suitable for use in natural gas TEG dehydration plants. The optimized steam regeneration method with dilute acid pre-treatment showed significant potential for improving the efficiency and sustainability of natural gas dehydration processes. These findings have important implications for the design and operation of steam regeneration units in industrial settings. Moreover, this study contributes to the growing body of research on sustainable and cost-effective methods for hydrocarbon removal in the gas processing industry.
引用
收藏
页码:109 / 119
页数:11
相关论文
共 36 条
[1]   Adsorption kinetics and thermodynamics of an anionic dye onto sepiolite [J].
Alkan, Mahir ;
Demirbas, Ozkan ;
Dogan, Mehmet .
MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 101 (03) :388-396
[2]   Comparison among Chemical, Thermal, and Electrochemical Regeneration of Phenol-Saturated Activated Carbon [J].
Berenguer, R. ;
Marco-Lozar, J. P. ;
Quijada, C. ;
Cazorla-Amoros, D. ;
Morallon, E. .
ENERGY & FUELS, 2010, 24 (06) :3366-3372
[3]   Optimization of process parameters for glycol unit to mitigate the emission of BTEX/VOCs [J].
Braek, AM ;
Almehaideb, RA ;
Darwish, N ;
Hughes, R .
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2001, 79 (B4) :218-232
[4]   Thermal regeneration study of high surface area activated carbon obtained from coconut shell: Characterization and application of response surface methodology [J].
Cazetta, Andre L. ;
Junior, Osvaldo P. ;
Vargas, Alexandro M. M. ;
da Silva, Aline P. ;
Zou, Xiaoxin ;
Asefa, Tewodros ;
Almeida, Vitor C. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 101 :53-60
[5]   Reactivation Process of Activated Carbons: Effect on the Mechanical and Adsorptive Properties [J].
Cevallos Toledo, Rita B. ;
Aragon-Tobar, Carlos F. ;
Gamez, Sebastian ;
de la Torre, Ernesto .
MOLECULES, 2020, 25 (07)
[6]   Optimization of triethylene glycol dehydration of natural gas [J].
Chebbi, Rachid ;
Qasim, Muhammad ;
Jabbar, Nabil Abdel .
ENERGY REPORTS, 2019, 5 :723-732
[7]  
Das S., 2017, Electronic Thesis and Dissertation Repository, V4721
[8]   Thermodynamics and kinetics of adsorption of a cationic dye onto sepiolite [J].
Demirbas, Ozkan ;
Turhan, Yasemin ;
Alkan, Mahir .
DESALINATION AND WATER TREATMENT, 2015, 54 (03) :707-714
[9]   Adsorption kinetics of maxilon blue GRL onto sepiolite from aqueous solutions [J].
Dogan, Mehmet ;
Alkan, Mahir ;
Demirbas, Ozkan ;
Ozdemir, Yasemin ;
Ozmetin, Cengiz .
CHEMICAL ENGINEERING JOURNAL, 2006, 124 (1-3) :89-101
[10]   Process optimization of thermal regeneration of spent coal based activated carbon using steam and application to methylene blue dye adsorption [J].
Duan Xin-hui ;
Srinivasakannan, C. ;
Liang Jin-sheng .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (04) :1618-1627