Efficient removal of cesium and strontium from an aqueous solution using a zirconosilicate/vanadium oxide nanocomposite

被引:6
|
作者
Bakhotmah, Dina A. [1 ]
Hussein, Mahmoud A. [1 ,2 ]
El-Said, Waleed [2 ,3 ]
Ismael, Mohamed H. [4 ]
Elshehy, Emad [4 ]
机构
[1] King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah, Saudi Arabia
[2] Assiut Univ, Fac Sci, Chem Dept, Assiut, Egypt
[3] Univ Jeddah, Fac Sci, Chem Dept, Jeddah, Saudi Arabia
[4] Nucl Mat Author NMA, POB 530, Cairo 11728, Egypt
关键词
Zeolite; zirconosilicate; cesium; strontium; radioactive waste; adsorption; RADIOACTIVE CESIUM; WASTE-WATER; ZIRCONIUM SILICATE; IONS; SEPARATION; DEHYDRATION; ADSORPTION; DECONTAMINATION; COMPOSITE; OXIDATION;
D O I
10.1080/01932691.2022.2048005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Here, we have reported a simple and one-step hydrothermal method for preparing a highly uniform sodium zirconosilicate mesoporous sorbent supported with vanadium oxide nanoparticles (VO2). The results showed the formation of NPs with a surface area of 73.21 m(2)/g and with a particle size ranged from 67 to 80 nm. Furthermore, the proposed fabricated composite has been used to significantly remove the cesium and strontium ions from the aqueous solution by a batch method. The phase and structural characteristics of the VO2/zirconosilicate nanocomposites were well studied by using XRD, SEM, HRTEM, and nitrogen adsorption techniques. The results showed that the cesium and strontium ions were efficiently adsorbed by mesoporous VO2/zirconosilicate ion exchanger at a natural and wide pH ranges. Various kinetic and isotherms models have been developed to highlight the adsorption process of cesium and strontium ions. The fabricated zeolitic materials exhibited an adsorption capacity of 30.5 and 22.2 mg g(-1) for Cs(I) and Sr(II), respectively. The collected data showed that the synthesized VO2/zirconosilicate has the maximum potential to properly remove Cs(I) and Sr(II) from the aqueous media.
引用
收藏
页码:1842 / 1852
页数:11
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