Synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes by cross-coupling induced by transition metals - formation of C-C bonds

被引:4
|
作者
Yasukawa, Tomohiro [1 ]
Haheim, Katja S. [1 ]
Cossy, Janine [1 ]
机构
[1] PSL, ESPCI Paris, Mol Macromol Chem & Mat, CNRS, F-75005 Paris, France
关键词
LIQUID-CRYSTALLINE; BRIDGEHEAD; ROUTE; ARYL; SALTS; SCOPE;
D O I
10.1039/d3ob01036h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes (BCPs), by forming a C-C bond, can be achieved by cross-coupling reactions using transition metal catalysts. Two main strategies are described to access these 1,3-disubstituted BCPs, either from nucleophilic BCPs or electrophilic BCPs. Mechanisms are included where relevant. The synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes (BCPs), by forming a C-C bond, can be achieved by cross-coupling reaction using transition metal catalysts.
引用
收藏
页码:7666 / 7680
页数:15
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