Meta-Aerogel Ion Motor for Nanofluid Osmotic Energy Harvesting

被引:13
作者
Zhang, Feng [1 ]
Yu, Jianyong [1 ,2 ]
Si, Yang [1 ,2 ]
Ding, Bin [1 ,2 ]
机构
[1] Donghua Univ, Coll Text, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
[2] Donghua Univ, Innovat Ctr Text Sci & Technol, Shanghai 200051, Peoples R China
基金
中国国家自然科学基金;
关键词
actuatable ion-highways; electrospinning; fibrous aerogels; nanofibers; nanofluidic cable fibers; osmotic energy; SALINITY GRADIENT; POWER-GENERATION; SELECTIVITY; CONVERSION; TRANSPORT; MEMBRANES; EELS;
D O I
10.1002/adma.202302511
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Osmotic power, also known as "blue energy", is a vast, sustainable, and clean energy source that can be directly converted into electricity by nanofluidic membranes. However, the key technological bottleneck for large-scale osmotic electricity is that macroscopic-scale bulky membrane cannot synergistically satisfy the demands of high power density and low resistance without sacrificing scalability and mechanical robustness. Here, inspired by the anatomy and working principle of electric eels, which harness osmotic energy through embedded neuron-mediated fibril nanochannels with nanoconfined transport dynamics. Fibrous nanofluidic meta-aerogel ion motors, 3D-assembled from nanofluidic cable fibers with actuatable stimulation/transport "ion highways" are engineered. The meta-aerogel exhibits the integrated coupling effect of boosted ion propulsion and surface-charge-dominated selective ion transport. Driven by osmosis, the meta-aerogel ion motor can produce an unprecedented output power density of up to 30.7 W m(-2) under a 50-fold salinity gradient. Advancing ultra-selective ion transport in nanofluidic meta-aerogels may provide a promising roadmap for blue energy harvesting.
引用
收藏
页数:10
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