Stereoselective oxidative O-glycosylation of disarmed glycosyl iodides with alcohols using PIDA as the promoter

被引：0

作者：

Boulogeorgou, Maria A. ^{[1
]}

Toskas, Alexandros ^{[1
]}

Gallos, John K. ^{[1
]}

Stathakis, Christos I. ^{[1
]}

机构：

[1] Aristotle Univ Thessaloniki, Dept Chem, Thessaloniki 54124, Greece

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 32期

关键词：

GLYCOSIDATION; BETA;

D O I：

10.1039/d3ob00929g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct and practical oxidative anomeric O-glycosylation of glycosyl iodides with an array of alcohols as glycosyl acceptors is presented. Using phenyliodine(iii) diacetate (PIDA) as the promoter of the reaction, at ambient temperature, an enviromentally benign and operationally simple protocol has been developed providing access stereoselectively to 1,2-trans-O-glycosides.

引用

页码：6479 / 6483

页数：5