Thermoelectric Properties of Ca0.5-xSr0.5LuxMnO3-δ Manganites

被引:1
作者
Konstantinova, E. I. [1 ]
Litvinov, V. A. [1 ]
Ryzhkov, M. A. [1 ,2 ]
Koryakov, A. D. [1 ]
Leonidov, I. A. [1 ]
机构
[1] Russian Acad Sci, Inst Solid State Chem, Ural Branch, Ekaterinburg 620108, Russia
[2] Yeltsin Fed Univ, Ekaterinburg 620002, Russia
基金
俄罗斯科学基金会;
关键词
perovskite-type manganites; electrical conductivity; Seebeck coefficient; specific heat; thermal expansion; POWER;
D O I
10.1134/S0020168523120051
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Using electrical conductivity (sigma), Seebeck coefficient (S), thermal expansion, specific heat, and thermal diffusivity measurements in air in the temperature range 300-1200 K, we have determined the thermal conductivity (kappa), thermoelectric power factor (S-2 sigma), and thermoelectric figure of merit (ZT = S-2 sigma T/kappa) of Ca0.5-xSr0.5LuxMnO3-delta (x = 0.05, 0.10, 0.15, 0.20) manganites. The Ca0.5-xSr0.5LuxMnO3-delta material has been shown to have the highest S2 sigma and ZT owing to its high S and low kappa.
引用
收藏
页码:1319 / 1325
页数:7
相关论文
共 27 条
[1]   Polarons in crystalline and non-crystalline materials [J].
Austin, IG ;
Mott, NF .
ADVANCES IN PHYSICS, 2001, 50 (07) :757-812
[2]   Thermoelectric and Magnetic Properties of Ca0.98RE0.02MnO3-δ (RE = Sm, Gd, and Dy) [J].
Bhaskar, Ankam ;
Liu, Chia-Jyi ;
Yuan, J. J. .
JOURNAL OF ELECTRONIC MATERIALS, 2012, 41 (09) :2338-2344
[3]   SMALL-POLARON VERSUS BAND CONDUCTION IN SOME TRANSITION-METAL OXIDES [J].
BOSMAN, AJ ;
VANDAAL, HJ .
ADVANCES IN PHYSICS, 1970, 19 (77) :1-&
[4]   Calcium manganite as oxygen electrode materials for reversible solid oxide fuel cell [J].
Chengsheng Ni ;
Irvine, John T. S. .
FARADAY DISCUSSIONS, 2015, 182 :289-305
[5]   Relationship between structural parameters and the Neel temperature in Sr1-xCaxMnO3 (0≤x≤1) and Sr1-yBayMnO3 (y≤0.2) -: art. no. 134412 [J].
Chmaissem, O ;
Dabrowski, B ;
Kolesnik, S ;
Mais, J ;
Brown, DE ;
Kruk, R ;
Prior, P ;
Pyles, B ;
Jorgensen, JD .
PHYSICAL REVIEW B, 2001, 64 (13)
[6]   THE ABSOLUTE SCALE OF THERMOELECTRIC POWER AT HIGH TEMPERATURE [J].
CUSACK, N ;
KENDALL, P .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1958, 72 (467) :898-901
[7]   Novel materials for solid oxide fuel cell technologies: A literature review [J].
da Silva, Fellipe Sartori ;
de Souza, Teofilo Miguel .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (41) :26020-26036
[8]   NONSTOICHIOMETRY IN PEROVSKITE-TYPE OXIDE CA1-XCEXMNO3-DELTA AND ITS PROPERTIES IN ALKALINE-SOLUTION [J].
ESAKA, T ;
MORIMOTO, H ;
IWAHARA, H .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (09) :821-824
[9]   Effect of Barium Concentration on the Structural Properties and Electrical Conductivity of Pr1-xBaxMnO3 (x=0, 0.15, 0.25) Solid Solutions [J].
Fedorova, O. M. ;
Vedmid, L. B. ;
Balakireva, V. B. ;
Vorotnikov, V. A. ;
Balakirev, V. F. .
INORGANIC MATERIALS, 2021, 57 (04) :392-398
[10]   Thermoelectric power of La1-xCaxMnO3+delta: Inadequacy of the nominal Mn3+/4+ valence approach [J].
Hundley, MF ;
Neumeier, JJ .
PHYSICAL REVIEW B, 1997, 55 (17) :11511-11515