An Amphiphilic Star-Shaped Polymer (Star-PEG-PCL2) used as a Stationary Phase for GC

被引：1

作者：

Chen, Ruo-nan ^{[1
]}

Cai, Zhi-qiang ^{[1
]}

Zhang, Wei ^{[1
]}

Huang, Qiu-chen ^{[1
]}

Li, Wei ^{[1
]}

Jin, Ke-yun ^{[2
]}

Zhao, Yi ^{[2
]}

Feng, Ge ^{[2
]}

Sun, Tao ^{[2
]}

机构：

[1] Shenyang Univ Technol, Liaoning Prov Profess & Tech Innovat Ctr Fine Chem, Sch Petrochem Engn, Liaoyang 111003, Peoples R China

[2] Luoyang Normal Univ, Coll Chem & Chem Engn, Henan Key Lab Funct Oriented Porous Mat, Luoyang 471934, Peoples R China

来源：

ACTA CHIMICA SLOVENICA | 2023年 / 70卷 / 01期

关键词：

Stationary phase; capillary gas chromatography; star-shaped polymer; separation performance; GAS-CHROMATOGRAPHY; PERFORMANCE; DERIVATIZATION; RELEASE; AMINES; WATER;

D O I：

10.17344/acsi.2022.7390

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A star-shaped polymer (Star-PEG-PCL2) was synthesized to with PCL and PEG, and used as a stationary phase for gas chromatography. The statically coated Star-PEG-PCL2 column exhibited an efficiency of 2260 plates/m determined by naphthalene at 120 & DEG;C and moderate polarity. The Star-PEG-PCL2 column showed high resolution performance for isomers of a wide ranging polarity, including methylnaphthalenes, halogenated benzenes, nitrobenzene, phenols, and anilines, and displayed dual-nature selectivity for a mixture of 17 analytes. Also, the Star-PEG-PCL2 column exhibited good separation performance and column inertness for Grob test mixture and a series of cis-/trans-isomers. In addition, it exhibited advantageous separation performance over the commercial HP-35 and PEG-20M columns for chloroaniline and bromoaniline isomers through its unique three-dimensional framework. In conclusion, it has good potential as a new stationary phase for separating a variety of analytes because of its special structure and excellent separation performance.

引用

页码：1 / 11

页数：11

共 50 条

[31] Targeted delivery of doxorubicin to human breast cancers by folate-decorated star-shaped PEG-PCL micelle
Nguyen-Van Cuong
Li, Yu-Lun
Hsieh, Ming-Fa
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (03) : 1006 - 1020
[32] Degradation behaviors of star-shaped PEG-b-PLLA copolymers
Lin, Y. (linyaling@scau.edu.cn), 1600, Sichuan University (29):
[33] A CHARACTERIZATION OF UNIONS OF 2 STAR-SHAPED SETS
KOCH, CF
MARR, JM
PROCEEDINGS OF THE AMERICAN MATHEMATICAL SOCIETY, 1966, 17 (06) : 1341 - +
[34] SYNTHESIS AND CHARACTERIZATION OF STAR-SHAPED POLYMER WITH ONE LABELED ARM
TAKANO, A
OKADA, M
NOSE, T
FUJIMOTO, T
MACROMOLECULES, 1992, 25 (13) : 3596 - 3598
[35] Star-shaped polymer translocation into a nanochannel: Langevin dynamics simulations
Tilahun, Mesay
Tatek, Yergou B.
PHYSICA SCRIPTA, 2023, 98 (02)
[36] Phase behavior, crystallization, and nanostructures in thermoset blends of epoxy resin and amphiphilic star-shaped block copolymers
Guo, QP
Wang, K
Chen, L
Zheng, SX
Halley, PJ
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2006, 44 (06) : 975 - 985
[37] Self-assembled biodegradable micelles based on star-shaped PCL-b-PEG copolymers for chemotherapeutic drug delivery
Dong, PengWei
Wang, XiuHong
Gu, YingChun
Wang, YuJun
Wang, YingJing
Gong, ChangYang
Luo, Feng
Guo, Gang
Zhao, Xia
Wei, YuQuan
Qian, ZhiYong
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2010, 358 (1-3) : 128 - 134
[38] Synthesis of eight- and star-shaped poly(ε-caprolactone)s and their amphiphilic derivatives
Li, Haiying
Riva, Raphael
Kricheldorf, Hans R.
Jerome, Robert
Lecomte, Philippe
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (01) : 358 - 368
[39] Folate-conjugated amphiphilic star-shaped block copolymers as targeted nanocarriers
Zhu, Jundong
Zhou, Zhichao
Yang, Cuihong
Kong, Deling
Wan, Ying
Wang, Zheng
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2011, 97A (04) : 498 - 508
[40] Synthesis and characterization of amphiphilic star-shaped polymers with calix[6]arene cores
Zhu, Weipu
Ling, Jun
Shen, Zhiquan
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2006, 207 (09) : 844 - 849

← 1 2 3 4 5 →