Oxidative N-Heterocyclic Carbene Catalysis

被引：31
|
作者：
De Risi, Carmela [1 ]
Brandolese, Arianna [2 ]
Di Carmine, Graziano [1 ]
Ragno, Daniele [1 ]
Massi, Alessandro [1 ]
Bortolini, Olga [2 ]
机构：
[1] Univ Ferrara, Dipartimento Sci Chim Farmaceut Agrarie, Via L Borsari, 46, I-44121 Ferrara, Italy
[2] Univ Ferrara, Dipartimento Sci Ambiente & Prevenz, Via L Borsari, 46, I-44121 Ferrara, Italy
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2023年 / 29卷 / 04期
关键词：
domino reactions; N-heterocyclic carbenes; organocatalysis; oxidation; synthetic methods; MULTISTEP ELECTRON-TRANSFER; ENANTIOSELECTIVE SYNTHESIS; AROMATIC-ALDEHYDES; AEROBIC OXIDATION; NHC-CATALYSIS; ALPHA; BETA-UNSATURATED ALDEHYDES; CHEMOSELECTIVE ACYLATION; DIRECT ESTERIFICATION; SMILES REARRANGEMENT; ASYMMETRIC-SYNTHESIS;
D O I：
10.1002/chem.202202467
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Oxidative N-heterocyclic carbene (NHC) catalysis offers the chance to perform oxidative and oxygenative transformations which give rise to various NHC-bound intermediates, paving the way to non-umpolung processes through activation of carbon atoms and heteroatoms. The aim of this review is to discuss the developments of the literature in the field of oxidative NHC-catalysis since 2014, with particular focus to pivotal intermediates and their mechanistic involvement. More information can be found in the Review article by C. De Risi and co-workers. (DOI: 10.1002/chem.202202467)
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页数：51
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