Oxidative N-Heterocyclic Carbene Catalysis

被引：31

作者：

De Risi, Carmela ^{[1
]}

Brandolese, Arianna ^{[2
]}

Di Carmine, Graziano ^{[1
]}

Ragno, Daniele ^{[1
]}

Massi, Alessandro ^{[1
]}

Bortolini, Olga ^{[2
]}

机构：

[1] Univ Ferrara, Dipartimento Sci Chim Farmaceut Agrarie, Via L Borsari, 46, I-44121 Ferrara, Italy

[2] Univ Ferrara, Dipartimento Sci Ambiente & Prevenz, Via L Borsari, 46, I-44121 Ferrara, Italy

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2023年 / 29卷 / 04期

关键词：

domino reactions; N-heterocyclic carbenes; organocatalysis; oxidation; synthetic methods; MULTISTEP ELECTRON-TRANSFER; ENANTIOSELECTIVE SYNTHESIS; AROMATIC-ALDEHYDES; AEROBIC OXIDATION; NHC-CATALYSIS; ALPHA; BETA-UNSATURATED ALDEHYDES; CHEMOSELECTIVE ACYLATION; DIRECT ESTERIFICATION; SMILES REARRANGEMENT; ASYMMETRIC-SYNTHESIS;

D O I：

10.1002/chem.202202467

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative N-heterocyclic carbene (NHC) catalysis offers the chance to perform oxidative and oxygenative transformations which give rise to various NHC-bound intermediates, paving the way to non-umpolung processes through activation of carbon atoms and heteroatoms. The aim of this review is to discuss the developments of the literature in the field of oxidative NHC-catalysis since 2014, with particular focus to pivotal intermediates and their mechanistic involvement. More information can be found in the Review article by C. De Risi and co-workers. (DOI: 10.1002/chem.202202467)

引用

页数：51

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