Oxidative N-Heterocyclic Carbene Catalysis

被引:0
作者
De Risi, Carmela [1 ]
Brandolese, Arianna [2 ]
Di Carmine, Graziano [1 ]
Ragno, Daniele [1 ]
Massi, Alessandro [1 ]
Bortolini, Olga [2 ]
机构
[1] Univ Ferrara, Dipartimento Sci Chim & Farmaceut Agr, Via L Borsari 46, I-44121 Ferrara, Italy
[2] Univ Ferrara, Dipartimento Sci Ambiente & Prevenz, Via L Borsari 46, I-44121 Ferrara, Italy
关键词
domino reactions; N-heterocyclic carbenes; organocatalysis; oxidation; synthetic methods;
D O I
10.1002/chem.202380461
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Oxidative N-heterocyclic carbene (NHC) catalysis offers the chance to perform oxidative and oxygenative transformations which give rise to various NHC-bound intermediates, paving the way to non-umpolung processes through activation of carbon atoms and heteroatoms. The aim of this review is to discuss the developments of the literature in the field of oxidative NHC-catalysis since 2014, with particular focus to pivotal intermediates and their mechanistic involvement. More information can be found in the Review article by C. De Risi and co-workers. (DOI: 10.1002/chem.202202467)
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页数:1
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