One-Pot Iron-Catalyzed Cross-Coupling Reactions of Aryl Chlorides and Aryl Bromides

被引:1
|
作者
Yin, Yi-Bing [1 ,2 ]
Peng, Xiao-Shui [1 ,2 ,3 ]
Wong, Henry N. C. [1 ,2 ,3 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China
[2] Chinese Univ Hong Kong, State Key Lab Synthet Chem, Hong Kong, Peoples R China
[3] Chinese Univ Hong Kong Shenzhen, Sch Sci & Engn, Shenzhen Key Lab Innovat Drug Synth, Shenzhen, Peoples R China
来源
SYNTHESIS-STUTTGART | 2023年 / 55卷 / 14期
基金
中国国家自然科学基金;
关键词
iron-catalyzed; cross-coupling; one-pot reaction; aryl chlorides; aryl bromides; HALIDES; REAGENTS; PALLADIUM;
D O I
10.1055/a-2042-3533
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A one-pot iron-catalyzed cross-coupling protocol involving aryl chlorides, aryl bromides and magnesium metal was developed to-wards the construction of unsymmetrical biaryls. The key procedure of this reaction is the in situ generation of Grignard reagents.
引用
收藏
页码:2253 / 2260
页数:8
相关论文
共 50 条
  • [1] Iron-Catalyzed Reductive Aryl-Alkenyl Cross-Coupling Reactions
    Czaplik, Waldemar M.
    Mayer, Matthias
    Jacobi von Wangelin, Axel
    CHEMCATCHEM, 2011, 3 (01) : 135 - 138
  • [2] Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignards with Aryl Chlorobenzenesulfonates
    Bisz, Elwira
    MOLECULES, 2021, 26 (19):
  • [3] Iron-Catalyzed Cross-Coupling of Diarylzinc or Aryl Grignard Reagents with Difluoroalkyl Bromides
    An Lun
    Tong Feifei
    Zhang Xingang
    ACTA CHIMICA SINICA, 2018, 76 (12) : 977 - 982
  • [4] Iron-Catalyzed Cross-Coupling of Benzylic Manganese Chlorides with Aryl and Heteroaryl Halides
    Benischke, Andreas D.
    Breuillac, Antoine J. A.
    Moyeux, Alban
    Cahiez, Gerard
    Knochel, Paul
    SYNLETT, 2016, 27 (03) : 471 - 476
  • [5] Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignards with Aryl Sulfamates and Tosylates
    Agrawal, Toolika
    Cook, Silas P.
    ORGANIC LETTERS, 2013, 15 (01) : 96 - 99
  • [6] Iron-catalyzed cross-coupling reactions of alkyl-grignard reagents with aryl chlorides, tosylates, and triflates
    Fürstner, A
    Leitner, A
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (04) : 609 - +
  • [7] Nickel-Catalyzed Direct Cross-Coupling of Aryl Fluorosulfates with Aryl Bromides
    Na, Jin-He
    Liu, Xiang
    Jing, Jia-Wen
    Wang, Jing
    Chu, Xue-Qiang
    Ma, Mengtao
    Xu, Hao
    Zhou, Xiaocong
    Shen, Zhi-Liang
    ORGANIC LETTERS, 2023, 25 (13) : 2318 - 2322
  • [8] Palladium-catalyzed cross-coupling of trimethoxysilylbenzene with aryl bromides and chlorides using phosphite ligands
    Ju, Jinhun
    Nam, Hyungoog
    Jung, Hyun Min
    Lee, Sunwoo
    TETRAHEDRON LETTERS, 2006, 47 (49) : 8673 - 8678
  • [9] Cobalt(II)-catalyzed cross-coupling of polyfunctional aryl copper reagents with aryl bromides and chlorides
    Korn, TJ
    Knochel, P
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (19) : 2947 - 2951
  • [10] Iron-Catalyzed Enantioselective Cross-Coupling Reactions of α-Chloroesters with Aryl Grignard Reagents
    Jin, Masayoshi
    Adak, Laksmikanta
    Nakamura, Masaharu
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (22) : 7128 - 7134