A hexaazatriphenylene-based polymer as high performance anode for Li-/Na-/K-ion batteries

被引:28
作者
Zou, Jincheng [1 ]
Fan, Kun [1 ,2 ]
Wang, Xiaobo [1 ]
Chen, Yuan [1 ,2 ]
Cao, Yueyue [1 ]
Dai, Huichao [1 ]
Zhang, Chenyang [1 ]
Fu, Manli [1 ]
Gao, Yanbo [1 ]
Liu, Huan [1 ,2 ]
Wang, Chengliang [1 ,2 ]
机构
[1] Huazhong Univ Sci & Technol, Sch Integrated Circuits, Sch Opt & Elect Informat, Wuhan Natl Lab Optoelect WNLO, Wuhan 430074, Peoples R China
[2] Huazhong Univ Sci & Technol, Wenzhou Adv Mfg Inst, Wenzhou 325035, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Organic batteries; Organic potassium-ion batteries; Organic sodium-ion batteries; Organic lithium-ion batteries; Hexaazatriphenylenes; COVALENT ORGANIC FRAMEWORKS; ENERGY-STORAGE; FAST-CHARGE; ELECTROCHEMICAL PROPERTIES; LITHIUM; BEHAVIOR; CATHODE;
D O I
10.1016/j.cej.2023.141703
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Organic electrodes have attracted a lot of attention in alkali metal-ion batteries recently due to their flexibility, potentially low cost, and environmental benignity compared to traditional inorganic materials. Even though alkali metal-ion batteries are supposed to be alike, the application of one organic electrode in different batteries was rarely reported and systematically investigated. Here, we report a hexaazatriphenylene-based polymer (HAT-PPDA) as anodes for Li-/Na-/K-ion batteries. The results showed that every hexaazatriphenylene imide unit could accept 6 electrons for Na-(SIBs) and K-ion batteries (PIBs); while it could accept 3 more electrons for Li-ion batteries (LIBs), yielding high reversible capacities of 405 mAh g(-1) in PIBs, 397 mAh g(-1) in SIBs and 681 mAh g(-1) in LIBs at 100 mA g(-1), respectively. Particularly, the performance of HAT-PPDA was superior to the previously reported organic anodes for PIBs. On the other hand, the rate performance of HAT-PPDA in SIBs was better than those in PIBs and LIBs. This work provides universal high performance anodes for Li-/Na-/K-ion batteries, reveals insights into the charge storage of organic electrodes in alkali metal-ion batteries and will guide the future development of organic materials for achieving high performance batteries.
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页数:9
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