Heterogeneous M-N-C Catalysts for Aerobic Oxidation Reactions: Lessons from Oxygen Reduction Electrocatalysts

被引：67

作者：

Bates, Jason S. ^{[1
]}

Johnson, Mathew R. ^{[1
]}

Khamespanah, Fatemeh ^{[1
]}

Root, Thatcher W. ^{[2
]}

Stahl, Shannon S. ^{[1
]}

机构：

[1] Univ Wisconsin Madison, Dept Chem, Madison, WI 53706 USA

[2] Univ Wisconsin Madison, Dept Chem & Biol Engn, Madison, WI 53706 USA

来源：

CHEMICAL REVIEWS | 2023年 / 123卷 / 09期

关键词：

ACTIVE-SITE DENSITY; NITROGEN-CARBON ELECTROCATALYSTS; FUNCTIONAL THEORY CALCULATIONS; SINGLE-ATOM CATALYSTS; IRON-BASED CATALYSTS; X-RAY-ABSORPTION; DOPED CARBON; SELECTIVE OXIDATION; COBALT NANOPARTICLES; MOSSBAUER-SPECTROSCOPY;

D O I：

10.1021/acs.chemrev.2c00424

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nonprecious metal heterogeneous catalysts composed of first-row transition metals incorporated into nitrogen-doped carbon matrices (M-N-Cs) have been studied for decades as leading alternatives to Pt for the electrocatalytic O2 reduction reaction (ORR). More recently, similar M-N-C catalysts have been shown to catalyze the aerobic oxidation of organic molecules. This Focus Review highlights mechanistic similarities and distinctions between these two reaction classes and then surveys the aerobic oxidation reactions catalyzed by M-N-Cs. As the active-site structures and kinetic properties of M-N-C aerobic oxidation catalysts have not been extensively studied, the array of tools and methods used to characterize ORR catalysts are presented with the goal of supporting further advances in the field of aerobic oxidation.

引用

页码：6233 / 6256

页数：24

共 220 条

[11] Quantification of Active Site Density and Turnover Frequency: From Single-Atom Metal to Nanoparticle Electrocatalysts
Bae, Geunsu
Kim, Haesol
Choi, Hansol
Jeong, Pyeonghwa
Kim, Dong Hyun
Kwon, Han Chang
Lee, Kug-Seung
Choi, Minkee
Oh, Hyung-Suk
Jaouen, Frederic
Choi, Chang Hyuck
[J]. JACS AU, 2021, 1 (05): : 586 - 597
[12] In situ X-ray absorption of a carbon monoxide-iron porphyrin adduct adsorbed on high-area carbon in an aqueous electrolyte
Bae, IT
Scherson, DA
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (14): : 2519 - 2522
[13] ELECTROCATALYSIS OF OXYGEN REDUCTION PROCESS ON METAL-CHELATES IN ACID ELECTROLYTE
BAGOTZKY, VS
TARASEVICH, MR
RADYUSHKINA, KA
LEVINA, OA
ANDRUSYOVA, SI
[J]. JOURNAL OF POWER SOURCES, 1978, 2 (03) : 233 - 240
[14] Efficient and selective aerobic oxidation of alcohols catalysed by MOF-derived Co catalysts
Bai, Cuihua
Li, Aiqin
Yao, Xianfang
Liu, Hongli
Li, Yingwei
[J]. GREEN CHEMISTRY, 2016, 18 (04) : 1061 - 1069
[15] Bard A.J., 2001, Electrochemical Methods: Fundamentals and Applications
[16] Chemical and Electrochemical O2 Reduction on Earth-Abundant M-N-C Catalysts and Implications for Mediated Electrolysis
Bates, Jason S.
Biswas, Sourav
Suh, Sung-Eun
Johnson, Mathew R.
Mondal, Biswajit
Root, Thatcher W.
Stahl, Shannon S.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (02) : 922 - 927
[17] Kinetic effects of molecular clustering and solvation by extended networks in zeolite acid catalysis
Bates, Jason S.
Gounder, Rajamani
[J]. CHEMICAL SCIENCE, 2021, 12 (13) : 4699 - 4708
[18] A link between reactivity and local structure in acid catalysis on zeolites
Bhan, Aditya
Iglesia, Enrique
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (04) : 559 - 567
[19] Does CO poison Fe-based catalysts for ORR?
Birry, Laurent
Zagal, Jose H.
Dodelet, Jean-Pol
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (05) : 628 - 631
[20] Deactivation, reactivation and super-activation of Fe-N/C oxygen reduction electrocatalysts: Gas sorption, physical and electrochemical investigation using NO and O2
Boldrin, Paul
Malko, Daniel
Mehmood, Asad
Kramm, Ulrike, I
Wagner, Stephan
Paul, Stephen
Weidler, Natascha
Kucernak, Anthony
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 292

← 1 2 3 4 5 6 7 8 9 10 →