Heterogeneous M-N-C Catalysts for Aerobic Oxidation Reactions: Lessons from Oxygen Reduction Electrocatalysts

被引：67
作者：
Bates, Jason S. [1 ]
Johnson, Mathew R. [1 ]
Khamespanah, Fatemeh [1 ]
Root, Thatcher W. [2 ]
Stahl, Shannon S. [1 ]
机构：
[1] Univ Wisconsin Madison, Dept Chem, Madison, WI 53706 USA
[2] Univ Wisconsin Madison, Dept Chem & Biol Engn, Madison, WI 53706 USA
来源：
CHEMICAL REVIEWS | 2023年 / 123卷 / 09期
关键词：
ACTIVE-SITE DENSITY; NITROGEN-CARBON ELECTROCATALYSTS; FUNCTIONAL THEORY CALCULATIONS; SINGLE-ATOM CATALYSTS; IRON-BASED CATALYSTS; X-RAY-ABSORPTION; DOPED CARBON; SELECTIVE OXIDATION; COBALT NANOPARTICLES; MOSSBAUER-SPECTROSCOPY;
D O I：
10.1021/acs.chemrev.2c00424
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nonprecious metal heterogeneous catalysts composed of first-row transition metals incorporated into nitrogen-doped carbon matrices (M-N-Cs) have been studied for decades as leading alternatives to Pt for the electrocatalytic O2 reduction reaction (ORR). More recently, similar M-N-C catalysts have been shown to catalyze the aerobic oxidation of organic molecules. This Focus Review highlights mechanistic similarities and distinctions between these two reaction classes and then surveys the aerobic oxidation reactions catalyzed by M-N-Cs. As the active-site structures and kinetic properties of M-N-C aerobic oxidation catalysts have not been extensively studied, the array of tools and methods used to characterize ORR catalysts are presented with the goal of supporting further advances in the field of aerobic oxidation.
引用
收藏
页码：6233 / 6256
页数：24
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