Luminescence-structure relationships in solids doped with Bi3+

被引：28

作者：

Boutinaud, Philippe ^{[1
]}

机构：

[1] Univ Clermont Auvergne, Clermont Auvergne INP, CNRS, ICCF, F-63000 Clermont Ferrand, France

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2023年 / 25卷 / 16期

关键词：

EXCELLENT THERMAL-STABILITY; NEAR-ULTRAVIOLET EXCITATION; EXCITED-STATE STRUCTURE; ENERGY-TRANSFER; CRYSTAL-STRUCTURE; DOUBLE-PEROVSKITE; PERSISTENT LUMINESCENCE; OPTICAL-PROPERTIES; EMITTING PHOSPHOR; PHOTOLUMINESCENCE PROPERTIES;

D O I：

10.1039/d3cp00289f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The luminescence properties of Bi3+ in 177 inorganic compounds are reviewed and rationalized based on two simple and easy-to-use models. These models are applicable to any kind of compound whose crystal structure is known. The calculation of the nephelauxetic function, he, involved in one of the models is described step-by-step for an easy implementation in a home-made calculator or machine-learning algorithm. Finally, a criterion based on the experimental value of the Stokes shift is introduced to help in fixing the origin of the Bi3+-related emission.

引用

页码：11027 / 11054

页数：28

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