Constructions of Fe3O4/HAp/Au nanohybrids with multifunctional structure for efficient photocatalysis and environmental remediation of organic dyes

被引:17
作者
Wu, Rui [1 ]
Song, Juan [1 ]
Lu, Jiufu [1 ]
Ji, Xiaohui [1 ]
Tian, Guanghui [1 ]
Zhang, Fagen [2 ]
机构
[1] Shaanxi Univ Technol, Coll Chem & Environm Sci, Shaanxi Key Lab Catalyt Fdn & Applicat, Hanzhong 723001, Peoples R China
[2] Guangzhou Univ, Sch Environm Sci & Engn, Guangzhou 510006, Peoples R China
关键词
Fe; 3; O; 4; HAp; Au; Nanoparticles; Photocatalysis; Methylene blue; DEGRADATION; NANOCOMPOSITES; ADSORPTION; REDUCTION; COMPOSITE;
D O I
10.1016/j.molstruc.2023.134908
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The controlled synthesis of nanohybrids with magnetic metal oxides (Fe3O4), noble metals Au, and hy-droxyapatite (HAp) have received considerable attention for applications in photocatalysis. Green and multifunctional Fe3O4/HAp/Au composite nanoparticles (NPs) was synthesized by facile method in the paper. The Fe3O4/HAp/Au was characterized by transmission electron microscopy(TEM), X-ray diffraction (XRD), UV, and the magnetic properties was measured. The nanohybrids (Fe3O4/HAp/Au) with biocom-patibility and magnetism for photocatalytic degradation of organic dyes was developed. The improvement performance of the Fe3O4/HAp/Au in photocatalysis was evaluated by degradation of organic dye (methy-lene blue, MB) under visible light irradiation. The results showed that the hybrid Fe3O4/HAp/Au NPs dis-played high photocatalytic activity. Also the possible mechanism was speculated. It proposed novel NPs and methodology to design and fabrication of multifunctional NPs with high quality for application in photocatalytic degradation. Furthermore, it is expected that the safe, green and multifunctional compos-ite NPs will provide an interesting platform not only for photocatalysis, but also for developing molecular imaging probe and drug delivery with target, as well as Raman detection.(c) 2023 Published by Elsevier B.V.
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页数:6
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共 48 条
[1]   Hydroxyapatite (HA)-based hybrid bionanocomposite hydrogels: Ciprofloxacin delivery, release kinetics and antibacterial activity [J].
Alinavaz, Samira ;
Mahdavinia, Gholam Reza ;
Jafari, Hessam ;
Hazrati, Maryam ;
Akbari, Ali .
JOURNAL OF MOLECULAR STRUCTURE, 2021, 1225
[2]   Rationally designed Ti3C2/N, S-TiO2/g-C3N4 ternary heterostructure with spatial charge separation for enhanced photocatalytic hydrogen evolution [J].
Biswal, Lijarani ;
Nayak, Susanginee ;
Parida, Kulamani .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2022, 621 :254-266
[3]   Sub-Band Gap Absorption Mechanisms Involving Oxygen Vacancies in Hydroxyapatite [J].
Bystrov, Vladimir S. ;
Avakyan, Leon A. ;
Paramonova, Ekaterina V. ;
Coutinho, Jose .
JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (08) :4856-4865
[4]   High catalytic activity of magnetic CuFe2O4/graphene oxide composite for the degradation of organic dyes under visible light irradiation [J].
Chen, Peng ;
Xing, Xiang ;
Xie, Huifang ;
Sheng, Qi ;
Qu, Hongxia .
CHEMICAL PHYSICS LETTERS, 2016, 660 :176-181
[5]   Performance improvement of Co3O4@nHAP hybrid nanomaterial in the UV light-supported degradation of organic pollutants and photovoltaics as counter electrode [J].
DAYAN, Serkan .
JOURNAL OF MOLECULAR STRUCTURE, 2021, 1238
[6]   Ligand-Exchange Assisted Formation of Au/TiO2 Schottky Contact for Visible-Light Photocatalysis [J].
Ding, Dawei ;
Liu, Kai ;
He, Shengnan ;
Gao, Chuanbo ;
Yin, Yadong .
NANO LETTERS, 2014, 14 (11) :6731-6736
[7]   Cocatalyst Modification of AgTaO3 Photocatalyst for Conversion of Carbon Dioxide with Water [J].
Guo, Qiaoqi ;
Xu, Jun ;
Luo, Ying ;
Yang, Yang ;
Wang, Zheng ;
He, Hong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2021, 125 (48) :26389-26397
[8]   Metal-Organic Gels of Catechol-Based Ligands with Ni(II) Acetate for Dye Adsorption [J].
Hong, Yue ;
Gao, Zhiliang ;
Chen, Mengjun ;
Hao, Jingcheng ;
Dong, Shuli .
LANGMUIR, 2018, 34 (32) :9435-9441
[9]   Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer [J].
James, Michael J. ;
Schwarz, Jonas Luca ;
Strieth-Kalthoff, Felix ;
Wibbeling, Birgit ;
Glorius, Frank .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (28) :8624-8628
[10]   Feasibility study on anaerobic biodegradation of azo dye reactive orange 16 [J].
Khan, Mohammad Zain ;
Singh, Satyendra ;
Sreekrishnan, T. R. ;
Ahammad, S. Z. .
RSC ADVANCES, 2014, 4 (87) :46851-46859