Suzuki Coupling in Troger's Bases: Overcoming Challenging Substrates through Aqueous Micellar Catalysis

被引：1
作者：
Boeira, Eduam O. [1 ]
Pla, Caroline B. [1 ]
Rodembusch, Fabiano S. [1 ]
Moro, Angelica, V [1 ]
机构：
[1] Univ Fed Rio Grande do Sul, Inst Chem, Av Ben Goncalves 9500, BR-91501970 Porto Alegre, RS, Brazil
来源：
CHEMCATCHEM | 2023年 / 15卷 / 03期
关键词：
Troger's base; Suzuki; Micellar catalysis; Palladium; FUNCTIONAL-GROUP ARRAYS; FACE AROMATIC INTERACTIONS; MOLECULAR RECOGNITION; SYNTHETIC RECEPTORS; FLUORESCENT-PROBE; ORGANIC FLUORINE; CROSS-COUPLINGS; CHEMISTRY; WATER; HYDROBORATION;
D O I：
10.1002/cctc.202201355
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Herein we report the arylation of Troger's base via the Suzuki cross-coupling reaction through aqueous micellar catalysis. The developed reaction conditions enabled us to prepare a variety of different derivatives with Troger's base skeleton, using a low catalytic loading of the readily available Pd(OAc)(2) catalyst and under environmentally friendly aqueous conditions.
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页数：6
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