Development of a back-arc basin from initial rifting to seafloor spreading: Constraints from Paleozoic basic rocks in the North Qinling accretionary orogen, central China

The progression from initial back -arc rifting to back -arc opening in ancient orogenic collages is important for reconstructing subduction histories, constraining tectonic switching, and understanding crustal growth and evolution. However, is difficult to constrain this transition in ancient arcs. The Qinling-Dabie orogenic belt is one of the most important orogenic belts in eastern Asia, yet the history of Paleozoic accretionary processes in this belt remains equivocal, owing to a poor understanding of back -arc opening processes in the Erlangping unit. In this study, we present whole -rock geochemical analyses of mafic dikes in the Erlangping unit, along with U-Pb ages and Hf-O isotope compositions of zircon from these dikes. Zircon secondary ion mass spectrometry (SIMS) dating of these mafic dikes yielded U-Pb ages of 453 +/- 3 Ma. The mafic dikes are calc-alkaline and are characterized by high K2O contents (1.16-3.16 wt%). They have enriched ([La/Yb]N = 4.3-14.9) light rare earth elements (REEs) and relatively flat heavy REE ([Dy/Yb]N = 0.9-1.5) patterns, and they exhibit enrichment in large ion lithophile elements (LILEs) but depletion in high field strength elements (HFSEs), resembling arc -like magmatism. These mafic dikes are characterized by relatively enriched initial 87Sr/86Sr (0.7049-0.7059), chondritic to slightly radiogenic epsilon Nd(t) (-0.36 to 1.33), and radiogenic whole-rock and zircon epsilon Hf(t) (+7.2-7.6 and +7.5-7.8, respectively). The zircons have delta 18O values (5.0 parts per thousand +/- 0.1 parts per thousand) similar to those of normal mantle zircon. Accordingly, we interpret that the mafic dikes were derived from an enriched lithospheric mantle source metasomatized by subducted Proto-Tethys (Shangdan) ocean material. In contrast, previously reported ca. 440 Ma gabbros from the Erlangping unit are tholeiitic and have lower incompatible trace-element concentrations with less enrichment in LILEs and less depletion in HFSEs than the mafic dikes presented here. Whole rock Nd and zircon Hf isotopic compositions suggest that these Silurian gabbros were derived from partial melting of a more depleted mantle with the involvement of asthenosphere, and they have a close geochemical affinity with back-arc basin basalts. In addition, trace-element ratios and geochemical modeling suggest higher melting pressures for the mafic dikes than the gabbros. The geochemical differences show systematic variations from island arc basalt into back-arc basin basalt types, which is consistent with the magma source evolution of the Mariana Trough. Thus, we interpret that the ca. 454 Ma mafic dikes were emplaced when the infant arc split, and they record initial back-arc rifting in the Erlangping unit, whereas the Silurian gabbros subsequently formed during the opening of the back-arc basin. Our study provides a paradigm for deciphering the evolution of back-arc basins through the study of spatiotemporal geological and geochemical variations of mafic intrusions in ancient accretionary orogens.