Amine-bearing cyclic ketene acetals for pH-responsive and degradable polyesters through radical ring-opening polymerisation

被引：6
|
作者：
Deng, Yiyi [1 ,2 ]
Frezel, Anais [1 ,2 ]
Mehner, Fabian [1 ,2 ]
Friedel, Peter [1 ]
Gaitzsch, Jens [1 ]
机构：
[1] Leibniz Inst Polymerforsch Dresden eV, Hohe Str 6, D-01069 Dresden, Germany
[2] Tech Univ Dresden, Berg Str 66, D-01069 Dresden, Germany
来源：
POLYMER CHEMISTRY | 2023年 / 14卷 / 37期
关键词：
BIODEGRADABLE NANOPARTICLES; COPOLYMERIZATION; POLYMERS; LIMITATIONS; DESIGN;
D O I：
10.1039/d3py00929g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of previously unreported amine-bearing cyclic ketene acetals (CKAs) furnished with different alkyl-substituents were prepared. These CKAs pave the way for a new range of pH-responsive and degradable polyesters from radical ring-opening polymerisation (RROP). CKA 2-methylene-1,3,6-trioxocane (MTC) was copolymerised with the amine-bearing CKAs to obtain a range of new degradable smart copolymers. Varying the type and amount of amine-bearing CKA allowed to fine-tune the value of the polymers, showcasing the versatility of this approach. A series of previously unreported amine-bearing cyclic ketene acetals (CKAs) furnished with different alkyl-substituents were prepared and polymerised into pH-responsive polyesters.
引用
收藏
页码：4275 / 4281
页数：7
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