Effect of CuO on physical, structural and optical properties of lithium borosilicate glasses

被引：15

作者：

Kaushik, Hariom Kumar ^{[1
,2
]}

Kaur, Amardeep ^{[3
]}

Garg, Vijay ^{[2
,4
]}

Abida, Km ^{[5
]}

Kumar, Sushil ^{[6
]}

Singh, K. ^{[7
]}

Singh, Supreet Pal ^{[3
]}

Khan, Savidh ^{[8
]}

机构：

[1] CCS Univ Meerut, Mhamana Malviya M M Degree Coll, Bagpat 250001, India

[2] CCS Univ Meerut, MM PG Coll Modinagar, Ghaziabad 250001, India

[3] Punjabi Univ, Dept Phys, Patiala 147002, Punjab, India

[4] CCS Univ Meerut, Kisan PG Coll Simbhaoli, Hapur 250001, India

[5] Swami Vivekanand Subharti Univ, Dept Chem, KVSCOS, Meerut 250005, Uttar Pradesh, India

[6] Dhanauri PG Coll Dhanauri, Haridwar 247667, Uttarakhand, India

[7] Thapar Inst Engn & Technol, Sch Phys & Mat Sci, Patiala 147004, Punjab, India

[8] RIMT Univ, Dept Phys, Mandi Gobindgarh 147301, Punjab, India

来源：

MATERIALS TODAY COMMUNICATIONS | 2023年 / 35卷

关键词：

Dielectric constant; Optical band gap; FTIR spectroscopy; X-ray diffraction; Refractive index; ELECTRONIC POLARIZABILITY; LEAD; BASICITY; CONDUCTIVITY; OXYGEN; STATE; Y2O3; IONS;

D O I：

10.1016/j.mtcomm.2023.106208

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

This paper reports the effect of copper on the physical, structural and optical properties of lithium borosilicate glasses with the composition of 50B2O3-30SiO2-(20-x) Li2O-xCuO (x = 2, 4, 6, 8, 10 mol %) synthesized by the conventional melt-quench technique. The prepared samples were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and UV-visible spectroscopy to study their structural and optical properties. Various physical parameters such as density, molar volume, oxygen packing density, ionic concentration and their inter-ionic distance are investigated. The band gap decreases from 3.64 to 2.70 eV with CuO doping into Li2O. The BO4 structural units change into BO3 units with the addition of CuO. The change in dielectric constant, extinction coefficient, refractive index and skin depth as a function of wavelength is also discussed. The theoretical optical basicity and oxide ion polarizability are found to increase with Li2O doping in place of CuO.

引用

页数：8

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