Metal-Catalyst-Controlled Divergent Synthesis of γ-Butyrolactones via Intramolecular Coupling of Epoxides with Alcohols

被引：1
作者：
Liu, Feipeng [1 ,2 ]
Cheng, Zifan [1 ,2 ]
Fang, Yiyun [1 ,2 ]
Wang, Xuchao [1 ,2 ]
Zhao, Lingzi [1 ,2 ]
Rong, Zi-Qiang [1 ,2 ]
机构：
[1] Northwestern Polytech Univ, Shaanxi Inst Flexible Elect SIFE, Frontiers Sci Ctr Flexible Elect FSCFE, Xian 710072, Peoples R China
[2] Northwestern Polytech Univ, Shaanxi Inst Biomed Mat & Engn SIBME, Xian 710072, Peoples R China
来源：
ORGANIC LETTERS | 2023年 / 25卷 / 20期
基金：
中国国家自然科学基金;
关键词：
BAEYER-VILLIGER OXIDATION; ASYMMETRIC EPOXIDATION; STYRENYL EPOXIDES; BETA-LACTONES; CARBONYLATION; FUNCTIONALIZATION; EFFICIENT; ALKENES; OLEFINS; ROUTE;
D O I：
10.1021/acs.orglett.3c00898
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A metal-controlled divergent protocol for the synthesisof alpha-and beta-substituted gamma-butyrolactones was developed throughintramolecular coupling of epoxides with alcohols. This method providesan efficient and practicable way to afford gamma-butyrolactoneswith good efficiency, excellent regioselectivity, and broad substratescope.
引用
收藏
页码：3618 / 3622
页数：5
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