Metal-Catalyst-Controlled Divergent Synthesis of γ-Butyrolactones via Intramolecular Coupling of Epoxides with Alcohols

被引：2

作者：

Liu, Feipeng ^{[1
,2
]}

Cheng, Zifan ^{[1
,2
]}

Fang, Yiyun ^{[1
,2
]}

Wang, Xuchao ^{[1
,2
]}

Zhao, Lingzi ^{[1
,2
]}

Rong, Zi-Qiang ^{[1
,2
]}

机构：

[1] Northwestern Polytech Univ, Shaanxi Inst Flexible Elect SIFE, Frontiers Sci Ctr Flexible Elect FSCFE, Xian 710072, Peoples R China

[2] Northwestern Polytech Univ, Shaanxi Inst Biomed Mat & Engn SIBME, Xian 710072, Peoples R China

来源：

ORGANIC LETTERS | 2023年 / 25卷 / 20期

基金：

中国国家自然科学基金;

关键词：

BAEYER-VILLIGER OXIDATION; ASYMMETRIC EPOXIDATION; STYRENYL EPOXIDES; BETA-LACTONES; CARBONYLATION; FUNCTIONALIZATION; EFFICIENT; ALKENES; OLEFINS; ROUTE;

D O I：

10.1021/acs.orglett.3c00898

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A metal-controlled divergent protocol for the synthesisof alpha-and beta-substituted gamma-butyrolactones was developed throughintramolecular coupling of epoxides with alcohols. This method providesan efficient and practicable way to afford gamma-butyrolactoneswith good efficiency, excellent regioselectivity, and broad substratescope.

引用

页码：3618 / 3622

页数：5

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