Palladium-Catalyzed Hydrophosphination of Terminal Alkynes with Diphenylphosphine Oxide in the Presence of Tetraphenyldiphosphine Monoxide

被引：4
作者：
Yamamoto, Yuki [1 ]
Fujiwara, Kohsuke [1 ]
Ogawa, Akiya [1 ,2 ]
机构：
[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan
[2] Osaka Metropolitan Univ, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan
来源：
ORGANOMETALLICS | 2023年 / 42卷 / 18期
基金：
日本学术振兴会;
关键词：
ASYMMETRIC HYDROPHOSPHORYLATION; PME3-CATALYZED ADDITION; STRAIGHTFORWARD ACCESS; PHOSPHINE OXIDES; P-C; EFFICIENT; ALKENES; ROUTE; BONDS; PHOSPHINYLPHOSPHINATION;
D O I：
10.1021/acs.organomet.2c00659
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this study, the Pd(OAc)2-catalyzed hydrophosphination of terminal alkynes was investigated in detail by using various diphosphines, which have a P-P bond, and the detailed mechanistic insights led to the successful development of a novel Pd-catalyzed hydrophosphination of terminal alkynes using Ph2P(O)H as both the phosphorus and hydrogen source. This catalytic transformation was successfully promoted in the presence of catalytic Ph2P(O)-PPh2, and the corresponding alkenylphosphine oxide was obtained in moderate to excellent yields with excellent product selectivity.
引用
收藏
页码：2590 / 2597
页数：8
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