Colorimetric Detection of Cu2+ and Ag+ Ions Using Multi-Responsive Schiff Base Chemosensor: A Versatile Approach for Environmental Monitoring

被引:5
|
作者
Abu-Taweel, Gasem Mohammad [1 ]
Al-Saidi, Hamed M. [2 ]
Alshareef, Mubark [3 ]
Alhamami, Mohsen A. M. [4 ]
Algethami, Jari S. [4 ,5 ]
Alharthi, Salman S. [6 ]
机构
[1] Jazan Univ, Dept Biol, Coll Sci, POB 2079, Jazan 45142, Saudi Arabia
[2] Umm Al Qura Univ, Univ Coll Al Jamoum, Dept Chem, Mecca 21955, Saudi Arabia
[3] Umm Al Qura Univ, Dept Chem, Fac Sci, Mecca 24230, Saudi Arabia
[4] Najran Univ, Dept Chem, Coll Arts & Sci, POB 1988, Najran 11001, Saudi Arabia
[5] Najran Univ, Adv Mat & Nano Res Ctr AMNRC, Najran 11001, Saudi Arabia
[6] Taif Univ, Dept Chem, Coll Sci, POB 11099, Taif 21944, Saudi Arabia
关键词
UV-vis spectroscopy; Schiff base; FT-IR; Chemosensor; Metal ions; HEAVY-METAL IONS; FLUORESCENT CHEMOSENSOR; SILVER ION; TURN-OFF; COPPER; TOXICITY; PROBE; QUANTIFICATION; NANOPARTICLES; SPECTROMETRY;
D O I
10.1007/s10895-023-03512-9
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
In this study, we have synthesized a novel Schiff base-centered chemosensor, designated as SB, with the chemical name ((E)-1-(((6-methylbenzo[d]thiazol-2-yl) imino)methyl)naphthalen-2-ol). This chemosensor was structurally characterized by FT-IR, 1H NMR, UV-Vis and fluorescence spectroscopy. After structural characterization the chemosensor SB was subsequently employed for the detection of Cu2+ and Ag+, using fluorescence spectroscopy. The chemosensor SB showed excellent ability to recognize the target metal ions, leading to fluorescence enhancement and color change from yellow to yellowish orange for Cu2+ and yellow to radish for Ag+ ions. The detection capabilities of this chemosensor were impressive, showing excellent selectivity and an exceptionally low detection limit of 0.0016 mu M for Cu2+ and 0.00389 mu M for Ag+. Most notably, our approach enables the quantitative detection both metal ions in different water and soil samples at trace level. This achievement holds great promise for analytical applications and offers significant contributions to the field of chemical sensing and environmental protection.
引用
收藏
页码:221 / 236
页数:16
相关论文
共 50 条
  • [1] A highly selective thiosemicarbazone based Schiff base chemosensor for colorimetric detection of Cu2+ and Ag+ ions and turn-on fluorometric detection of Ag+ ions
    Sahu, Meman
    Manna, Amit Kumar
    Rout, Kalyani
    Mondal, Jahangir
    Patra, Goutam K.
    INORGANICA CHIMICA ACTA, 2020, 508
  • [2] Determination of trace amount of Cu2+ with a multi-responsive colorimetric and reversible chemosensor
    Mi, Yong-Sheng
    Cao, Zhong
    Chen, Ya-Ting
    Xie, Qiu-Fen
    Xu, Ying-Ying
    Luo, Yong-Feng
    Shi, Jian-Jian
    Xiang, Jian-Nan
    ANALYST, 2013, 138 (18) : 5274 - 5280
  • [3] Highly selective colorimetric schiff base chemosensor for detection of Cu2+
    Liu, Dan
    Zhu, Hua
    Yang, Li
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2018, 57 (04): : 490 - 494
  • [4] Highly Selective and Sensitive Colorimetric and Fluorescent Chemosensor for Rapid Detection of Ag+, Cu2+ and Hg2+ Based on a Simple Schiff Base
    Shanshan Zhang
    Xingxing Wu
    Qingfen Niu
    Zongrang Guo
    Tianduo Li
    Haixia Liu
    Journal of Fluorescence, 2017, 27 : 729 - 737
  • [5] An innovative Schiff-base colorimetric chemosensor for the selective detection of Cu2+ ions and its applications
    Kumar, Ram
    Singh, Bholey
    Gahlyan, Parveen
    Verma, Abhishek
    Bhandari, Mamta
    Kakkar, Rita
    Pani, Balaram
    RSC ADVANCES, 2024, 14 (32) : 23083 - 23094
  • [6] Highly Selective and Sensitive Colorimetric and Fluorescent Chemosensor for Rapid Detection of Ag+, Cu2+ and Hg2+ Based on a Simple Schiff Base
    Zhang, Shanshan
    Wu, Xingxing
    Niu, Qingfen
    Guo, Zongrang
    Li, Tianduo
    Liu, Haixia
    JOURNAL OF FLUORESCENCE, 2017, 27 (02) : 729 - 737
  • [7] A benzoindo-croconine based colorimetric and fluorescent chemosensor for detection Fe3+/Cu2+/Ag+ ions
    Wang, Su
    Cong, Tiantian
    Liang, Qian
    Li, Zhongyu
    Xu, Song
    OPTIK, 2016, 127 (02): : 890 - 895
  • [8] Colorimetric detection of cyanide ions using Schiff base derived chemosensor
    Rahaman, Fazlur
    Gautam, Prabhat
    Mondal, Subrata
    Gupta, Priti
    MATERIALS TODAY-PROCEEDINGS, 2022, 62 : 5589 - 5592
  • [9] Development of 2-hydroxy-naphthaldehyde functionalized Schiff base chemosensor for spectroscopic and colorimetric detection of Cu2+ and Pd2+ ions
    Kumar, Ashwani
    Virender
    Mohan, Brij
    Solovev, Alexander A.
    Saini, Mohit
    Sharma, Harish Kumar
    MICROCHEMICAL JOURNAL, 2022, 180
  • [10] Synthesis, characterization and applications of schiff base chemosensor for determination of Cu2+ ions
    Khan, Sikandar
    Muhammad, Mian
    Al-Saidi, Hamed M.
    Hassanian, Athar Abdulfattah
    Alharbi, Walaa
    Alharbi, Khadijah H.
    JOURNAL OF SAUDI CHEMICAL SOCIETY, 2022, 26 (04)