Colorimetric Detection of Cu2+ and Ag+ Ions Using Multi-Responsive Schiff Base Chemosensor: A Versatile Approach for Environmental Monitoring

被引:7
作者
Abu-Taweel, Gasem Mohammad [1 ]
Al-Saidi, Hamed M. [2 ]
Alshareef, Mubark [3 ]
Alhamami, Mohsen A. M. [4 ]
Algethami, Jari S. [4 ,5 ]
Alharthi, Salman S. [6 ]
机构
[1] Jazan Univ, Dept Biol, Coll Sci, POB 2079, Jazan 45142, Saudi Arabia
[2] Umm Al Qura Univ, Univ Coll Al Jamoum, Dept Chem, Mecca 21955, Saudi Arabia
[3] Umm Al Qura Univ, Dept Chem, Fac Sci, Mecca 24230, Saudi Arabia
[4] Najran Univ, Dept Chem, Coll Arts & Sci, POB 1988, Najran 11001, Saudi Arabia
[5] Najran Univ, Adv Mat & Nano Res Ctr AMNRC, Najran 11001, Saudi Arabia
[6] Taif Univ, Dept Chem, Coll Sci, POB 11099, Taif 21944, Saudi Arabia
关键词
UV-vis spectroscopy; Schiff base; FT-IR; Chemosensor; Metal ions; HEAVY-METAL IONS; FLUORESCENT CHEMOSENSOR; SILVER ION; TURN-OFF; COPPER; TOXICITY; PROBE; QUANTIFICATION; NANOPARTICLES; SPECTROMETRY;
D O I
10.1007/s10895-023-03512-9
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
In this study, we have synthesized a novel Schiff base-centered chemosensor, designated as SB, with the chemical name ((E)-1-(((6-methylbenzo[d]thiazol-2-yl) imino)methyl)naphthalen-2-ol). This chemosensor was structurally characterized by FT-IR, 1H NMR, UV-Vis and fluorescence spectroscopy. After structural characterization the chemosensor SB was subsequently employed for the detection of Cu2+ and Ag+, using fluorescence spectroscopy. The chemosensor SB showed excellent ability to recognize the target metal ions, leading to fluorescence enhancement and color change from yellow to yellowish orange for Cu2+ and yellow to radish for Ag+ ions. The detection capabilities of this chemosensor were impressive, showing excellent selectivity and an exceptionally low detection limit of 0.0016 mu M for Cu2+ and 0.00389 mu M for Ag+. Most notably, our approach enables the quantitative detection both metal ions in different water and soil samples at trace level. This achievement holds great promise for analytical applications and offers significant contributions to the field of chemical sensing and environmental protection.
引用
收藏
页码:221 / 236
页数:16
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